Tricyclo[4.4.0.03,9]decane

Base Information

Chemical Name:Tricyclo[4.4.0.03,9]decane
CAS No.:29185-96-4
Molecular Formula:C10H16
Molecular Weight:136.237
Hs Code.:2902199090
Mol file:29185-96-4.mol

Synonyms:Tricyclo[4.4.0.03,9]decane

Suppliers and Price of Tricyclo[4.4.0.03,9]decane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Tricyclo[4.4.0.03,9]decane

Chemical Property:

PSA：0.00000
LogP:2.83260

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Tricyclo[4.4.0.03,9]decane

There total 17 articles about Tricyclo[4.4.0.03,9]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: tricyclo<4.4.0.0^3,9>decan-4-one

: 29185-96-4
2-homotwistbrendane

Guidance literature:: With potassium hydroxide; hydrazine hydrate; In diethylene glycol; 1.) 125 deg C, 45 min; 2.) up to 215 deg C within 30 min; 215 deg C, 1 h;
DOI:10.1002/hlca.19850680519

Reference yield: 54.0%

: tricyclo<4.4.0.0^3,9>dec-4-ene

: 29185-96-4
2-homotwistbrendane

Guidance literature:: With hydrogen; palladium on activated charcoal; In pentane;
DOI:10.1002/hlca.19850680519

Reference yield:

: 2903-75-5
(1S,2S,4S)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

: 29185-96-4
2-homotwistbrendane

Guidance literature:: Multi-step reaction with 13 steps

1: NaOCH₃ / hexane / -10 to 0 deg C, 2.5 h; up to r.t. within 30 min; r.t. 20 h

2: acetone / 1.) reflux, 9 h; 2.) r.t. 10 h

3: K₂CO₃ / methanol; H₂O / Ambient temperature

4: 1.) HMPA, 100 deg C, 27 h

5: 100 percent / H₂, pyrrolidine / 5 percent Pd/CaCO₃ / methanol / 2.25 h / Ambient temperature

6: DIBAH / diethyl ether / -78 deg C, 0.75 h; up to r.t. within 1.5 h; r.t. 2.5 h

7: Jones reagent / acetone / 0.75 h / Ambient temperature

8: diethyl ether

9: 45.5 percent / Na / toluene / 21 h / Heating

10: 1.) H₂, 2.) LiAlH₄ / 1.) 10 percent Pd/C / 1.) CH₃OH, r.t. 1 h; 2.) Et₂O, 0 deg C, 10 min; r.t. 45 min

11: 100 percent / p-(N,N-dimethylamino)pyridine / 5.5 h / Ambient temperature

12: 43.5 percent / Na, anthracene / tetrahydrofuran / 17 h / Ambient temperature

13: 54 percent / H₂ / 5 percent Pd/C / pentane

With pyrrolidine; dmap; lithium aluminium tetrahydride; jones reagent; anthracene; hydrogen; sodium methylate; sodium; diisobutylaluminium hydride; potassium carbonate; palladium on activated charcoal; Lindlar's catalyst; In tetrahydrofuran; methanol; diethyl ether; hexane; water; acetone; toluene; pentane;
DOI:10.1002/hlca.19850680519