(-)-1-Acenaphthenecarboxylic acid

Base Information

• Chemical Name: (-)-1-Acenaphthenecarboxylic acid
• CAS No.: 85977-56-6
• Molecular Formula: C₁₃H₁₀O₂
• Molecular Weight: 198.221
• Mol file: 85977-56-6.mol

Synonyms:

Chemical Property of (-)-1-Acenaphthenecarboxylic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-1-Acenaphthenecarboxylic acid

There total 15 articles about (-)-1-Acenaphthenecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

acenaphthene-1-carboxylic acid methyl ester (40745-41-3,129356-24-7,601469-86-7) → Acenaphthen-1-carbonsaeure (6833-51-8,85977-56-6,85977-57-7)

Guidance literature:

With potassium hydroxide; for 3h; Heating;

DOI:10.1055/s-1990-26925

Reference yield: 93.0%

1,2-dihydroacenaphthylene-1-carbonitrile (40745-39-9) → Acenaphthen-1-carbonsaeure (6833-51-8,85977-56-6,85977-57-7)

Guidance literature:

With sodium hydroxide; for 8h; Heating;

DOI:10.1055/s-1988-27742

Reference yield: 92.0%

Acenaphthylene-1-carboxylic acid (39653-73-1) → Acenaphthen-1-carbonsaeure (6833-51-8,85977-56-6,85977-57-7)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; for 3h; under 2068.6 Torr; Ambient temperature;

DOI:10.1021/jo00099a047

upstream raw materials:

1,2-dihydroacenaphthylene-1-carbonitrile

acenaphthene-1-carboxylic acid methyl ester

Acenaphthylene-1-carboxylic acid

1-bromoacenaphthylene

Refernces

• 1、 Sugimura, Takashi,Uchida, Takayuki,Watanabe, Junya,Kubota, Takeshi,Okamoto, Yasuaki,Misaki, Tomonori,Okuyama, Tadashi. "Structural requirements for substrate in highly enantioselective hydrogenation over the cinchonidine-modified Pd/C". experimental part. p. 57 - 64. Retrieved 2009/06/17.
• 2、 Halfpenny, Paul R.,Horwell, David C.,Rees, David C.. "Synthesis of Acenaphthene-1-carboxylic Acid Using Lithiated Tris(methylthio)methane to Carboxylate 1-Bromoacenaphthene". . p. 517 - 519. Retrieved 2007/10/02.