tert-Butyldimethylsilyl chloroacetate

Base Information

Chemical Name:tert-Butyldimethylsilyl chloroacetate
CAS No.:480439-47-2
Molecular Formula:C₈H₁₇ClO₂Si
Molecular Weight:208.76
Hs Code.:
DSSTox Substance ID:DTXSID80401511
Nikkaji Number:J455.960F
Wikidata:Q82204658
Mol file:480439-47-2.mol

Synonyms:tert-Butyldimethylsilyl chloroacetate;480439-47-2;[tert-butyl(dimethyl)silyl] 2-chloroacetate;tert-Butyldimethylsilyl 2-chloroacetate;DTXSID80401511;RUQHLZVDTNJVOW-UHFFFAOYSA-N;Chloroacetic acid, TBDMS derivative;tert-Butyldimethylsilyl chloroacetate, 97%

Suppliers and Price of tert-Butyldimethylsilyl chloroacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
tert-Butyldimethylsilyl chloroacetate 97%
5g
$ 62.80

American Custom Chemicals Corporation
TERT-BUTYLDIMETHYLSILYL CHLOROACETATE 95.00%
5G
$ 857.78

Total 5 raw suppliers

Chemical Property of tert-Butyldimethylsilyl chloroacetate

Chemical Property:

Vapor Pressure:0.669mmHg at 25°C
Refractive Index:n20/D 1.437(lit.)
Boiling Point:48-49 °C0.2 mm Hg(lit.)
Flash Point:154 °F
PSA：26.30000
Density:1.001 g/mL at 25 °C(lit.)
LogP:2.77360
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:208.0686340
Heavy Atom Count:12
Complexity:172

Purity/Quality:

98%Min ^*data from raw suppliers

tert-Butyldimethylsilyl chloroacetate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC(=O)CCl

Technology Process of tert-Butyldimethylsilyl chloroacetate

There total 4 articles about tert-Butyldimethylsilyl chloroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7748-25-6
potassium chloroacetate

: 98525-64-5
tert-butyldimethyl-(3-nitrophenoxy)silane

: 554-84-7
meta-nitrophenol

: 480439-47-2
C₈H₁₇ClO₂Si

Guidance literature:: With 18-crown-6 ether; potassium perchlorate; In N,N-dimethyl-formamide; at 30 ℃; Rate constant; Mechanism;
DOI:10.1021/jo00029a056

Reference yield:

: 126644-72-2
1-<(tert-butyldimethylsilyl)oxy>-4-chlorobenzene

: 7748-25-6
potassium chloroacetate

: 106-48-9,82344-39-6
4-chloro-phenol

: 480439-47-2
C₈H₁₇ClO₂Si

Guidance literature:: With 18-crown-6 ether; potassium perchlorate; In N,N-dimethyl-formamide; at 30 ℃; Rate constant; Mechanism;
DOI:10.1021/jo00029a056

Reference yield:

: 126644-71-1
1-<(tert-butyldimethylsilyl)oxy>-3-chlorobenzene

: 7748-25-6
potassium chloroacetate

: 108-43-0
3-monochlorophenol

: 480439-47-2
C₈H₁₇ClO₂Si

Guidance literature:: With 18-crown-6 ether; potassium perchlorate; In N,N-dimethyl-formamide; at 30 ℃; Rate constant; Mechanism;
DOI:10.1021/jo00029a056