126644-72-2

Basic information

• Product Name: Silane, (4-chlorophenoxy)(1,1-dimethylethyl)dimethyl-
• CAS NO: 126644-72-2
• Molecular Formula: C12H19ClOSi
• Molecular Weight: 242.821
• Mol File: 126644-72-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, (4-chlorophenoxy)(1,1-dimethylethyl)dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (4-chlorophenoxy)(1,1-dimethylethyl)dimethyl-(126644-72-2)
• EPA Substance Registry System: Silane, (4-chlorophenoxy)(1,1-dimethylethyl)dimethyl-(126644-72-2)

Safety Data

• Hazardous Substances Data: 126644-72-2(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 106-48-9 4-chloro-phenol 

Downstream Products

• 106-48-9 4-chloro-phenol 
• 876-27-7 4-chlorophenyl acetate 
• 117635-43-5 tert-butyl(4-(1-isocyanovinyl)phenoxy)dimethylsilane 
• 143106-12-1 tert-butyldimethyl(4-trimethylsilylphenoxy)silane 
• 18052-27-2 tert-butyldimethyl(phenoxy)silane 
• 873426-76-7 tert-butyldimethylsilyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl ether 
• 365448-17-5 C₁₂H₁₉ClOSiZn 
• 126644-91-5 1-chloro-4-methoxy-2-<2-(phenylsulfonyl)ethyl>benzene 
• 5257-08-9 3-methyl-6-hydroxycarbazol 
• 1836-74-4 4-(4-chlorophenoxy)nitrobenzene 
• 39145-47-6 1-(4-chlorophenoxy)-2-nitrobenzene 
• 200625-51-0 [{4-(1,1-dimethylethyl)dimethylsiloxyphenyl}ethynyl]trimethylsilane 
• 151692-21-6 (3-bromo-4-chloro-phenoxy)-tert-butyl-dimethyl-silane 
• 480439-47-2 C₈H₁₇ClO₂Si 

Relevant articles and documents

NFSI/KF mediated mild and chemoselective interconversion of aryl TBDMS ethers to their benzene sulfonate

A one pot protocol for the transformation of aryl TBDMS ethers to corresponding benzene sulfonate esters using NFSI (N-flurobenzenesulfonimide)/KF is described. In situ generation of benzenesulfonyl fluoride directs chemoselective cleavage of aryl silyl ethers over alkyl silyl ethers. Electron withdrawing substituent's on aryl ring provided better yield than donating groups. Protecting groups and sensitive functionalities are well tolerated in this methodology. Thus, commercially available inexpensive reagents, mild reaction conditions and step economy are the advantages of this method.

A mild and highly efficient method for the preparation of silyl ethers using Fe(HSO4)3/Et3N by chlorosilanes

Avery efficient and mild procedure for preparation of silyl ethers from benzylic, allylic, propargilic alcohols, phenols, naphtoles and some of phenolic drugs with trimethylsilylchloride (TMSCl), triethylsilylchloride (TESCl) and t-buthyldimethylsilyl chloride (TDSCl) ethers in the presence of Fe(HSO 4)3/Et3N in roomtemperature in excellent yields is reported. This procedure also allows the excellent selectivity for silylation of alcohols and phenols.

Electron-Rich 0 = PR3 compounds: Catalysts for alcohol silylation

The catalytic effect of a group of R3P = O compounds was studied in a mild procedure for the silylation of primary alcohols, secondary alcohols, hindered secondary alcohols, and of hindered phenols in the presence of t-butyldimethylsilyl chlori