11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS

Base Information

• Chemical Name: 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS
• CAS No.: 1166994-78-0
• Molecular Formula: C35H39OP
• Molecular Weight: 506.66
• Mol file: 1166994-78-0.mol

Synonyms:11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS;11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct

Chemical Property of 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS

Chemical Property:

• Boiling Point: 617.3±55.0 °C(Predicted)
• PSA: 22.82000
• LogP: 9.84460

Purity/Quality:

97% ^*data from raw suppliers

11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO-KITPHOS ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS

There total 1 articles about 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO KITPHOS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

11-(dicyclohexylphosphinoyl)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene (1166994-75-7) → 11-(dicyclohexylphosphino)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene (1166994-78-0)

Guidance literature:

With trichlorosilane; triethylamine; In toluene; at 110 ℃; for 72h;

DOI:10.1002/adsc.200800307

Reference yield: 84.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + 11-(dicyclohexylphosphino)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene (1166994-78-0) → [(11-(dicyclohexylphosphino)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene)AuCl] (1188507-63-2)

Guidance literature:

In dichloromethane; under inert atm. to soln. Au(tht)Cl in CH2Cl2 soln. ligand in CH2Cl2 wasadded, stirred for 1 h; solvent was removed in vacuo, residue was triturated with Et2O, slow diffusion hexane into CHCl3 soln.; elem. anal.;

DOI:10.1021/om1006769

upstream raw materials:

11-(dicyclohexylphosphinoyl)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene

Downstream raw materials:

[(11-(dicyclohexylphosphino)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene)AuCl]

Refernces