Nitrone, alpha-(m-nitrophenyl)-N-phenyl-

Base Information

• Chemical Name: Nitrone, alpha-(m-nitrophenyl)-N-phenyl-
• CAS No.: 19865-57-7
• Molecular Formula: C₁₃H₁₀N₂O₃
• Molecular Weight: 242.234
• NSC Number: 102885
• Mol file: 19865-57-7.mol

Synonyms:94664-75-2;Nitrone, alpha-(m-nitrophenyl)-N-phenyl-;1-(3-nitrophenyl)-N-phenylmethanimine oxide;(NZ)-N-[(3-NITROPHENYL)METHYLIDENE]-N-OXIDOANILINIUM;19865-57-7;Nitrone, .alpha.-(m-nitrophenyl)-N-phenyl-;NSC102885;(Z)-N-(3-nitrobenzylidene)aniline oxide;Benzenamine, N-[(3-nitrophenyl)methylene]-, N-oxide;SCHEMBL12416780;STK088313;AKOS001036251;NSC-102885;.alpha.-3'-Nitrophenyl N-phenylnitrone;.alpha.-(m-Nitrophenyl)-N-phenylnitrone;SR-01000010209;SR-01000010209-1;Z56803517;F1065-0161;N-[(Z)-(3-nitrophenyl)methylidene]-N-phenylamine oxide

Chemical Property of Nitrone, alpha-(m-nitrophenyl)-N-phenyl-

Chemical Property:

• Vapor Pressure: 3.76E-07mmHg at 25°C
• Boiling Point: 428.5°Cat760mmHg
• Flash Point: 212.3°C
• PSA: 74.57000
• Density: 1.311g/cm³
• LogP: 3.90210
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 242.06914219
• Heavy Atom Count: 18
• Complexity: 319

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[N+](=CC2=CC(=CC=C2)[N+](=O)[O-])[O-]
• Isomeric SMILES: C1=CC=C(C=C1)/[N+](=C/C2=CC(=CC=C2)[N+](=O)[O-])/[O-]

Technology Process of Nitrone, alpha-(m-nitrophenyl)-N-phenyl-

There total 8 articles about Nitrone, alpha-(m-nitrophenyl)-N-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-nitro-benzaldehyde (99-61-6) + N-Phenylhydroxylamine (100-65-2) → 1-(3-nitrophenyl)-N-phenylmethanimine oxide (19865-57-7,94664-75-2)

Guidance literature:

In glycerol; at 60 - 80 ℃; for 0.333333h; Green chemistry;

DOI:10.1007/s12039-019-1677-7

Reference yield: 85.0%

3-nitro-benzaldehyde (99-61-6) + N-Phenylhydroxylamine (100-65-2) → 3-nitro-benzaldehyde-(N-phenyl oxime ) (19865-57-7,94664-75-2)

Guidance literature:

In ethanol; for 4h; Ambient temperature;

Reference yield: 79.0%

C13H10N4O6S + Nitrosobenzene (586-96-9) → 3-nitro-benzaldehyde-(N-phenyl oxime ) (19865-57-7,94664-75-2)

Guidance literature:

With sodium hydride; In dichloromethane; mineral oil; at 40 ℃; for 16h; Inert atmosphere; Sealed tube;

DOI:10.1055/s-0036-1591757

upstream raw materials:

3-nitro-benzaldehyde

N-Phenylhydroxylamine

nitrobenzene

Nitrosobenzene

Downstream raw materials:

3-nitrophenyl-(bis-3-indolyl)methane

3,3'-((3-nitrophenyl)methylene)bis(2-methyl-1H-indole)

3-(m-nitrophenyl)-2-phenyl-5-(tricyanovinyl)-Δ⁴-1,2,4-oxadiazoline

3-(3-Nitro-phenyl)-2-phenyl-tetrahydro-furo[3,4-d]isoxazol-4-one

Refernces

• 1、 Shariatipour, Monire,Jadidinejad, Masoumeh,Heydari, Akbar. "A green synthesis of nitrones in glycerol". . . Retrieved 2019/11/11.
• 2、 Liu, Tingting,Liu, Zhaohong,Liu, Zhenhua,Hu, Donghua,Wang, Yeming. "Coupling of N -Nosylhydrazones with Nitrosoarenes: Transition-Metal-Free Approach to (Z)- N -Arylnitrones". supporting information. p. 1728 - 1736. Retrieved 2018/02/14.