DODECA-2(E),4(E)-DIENOIC ACID(SG)

Base Information

• Chemical Name: DODECA-2(E),4(E)-DIENOIC ACID(SG)
• CAS No.: 24738-48-5
• Molecular Formula: C12H20O2
• Molecular Weight: 196.29
• Mol file: 24738-48-5.mol

Synonyms:DODECA-2(E),4(E)-DIENOIC ACID(SG)

Chemical Property of DODECA-2(E),4(E)-DIENOIC ACID(SG)

Chemical Property:

• Melting Point: 35 °C
• PSA: 37.30000
• LogP: 3.54390

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DODECA-2(E),4(E)-DIENOIC ACID(SG)

There total 11 articles about DODECA-2(E),4(E)-DIENOIC ACID(SG) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(2E,4E)-dodecadien-2,4-oic acid ethyl ester (39924-20-4) → 2,4-dodecadienoic acid (24738-48-5)

Guidance literature:

With water; sodium hydroxide; In methanol;

Reference yield: 94.9%

methyl (E,E)-dodeca-2,4-dienoate (24738-46-3) → 2,4-dodecadienoic acid (24738-48-5)

Guidance literature:

With potassium hydroxide; In ethanol; at 60 ℃; for 0.666667h;

DOI:10.7164/antibiotics.48.1467

Reference yield: 85.0%

2-methyl-but-2-ene (513-35-9) + trans,trans-2,4-dodecadienal (21662-16-8) → 2,4-dodecadienoic acid (24738-48-5)

Guidance literature:

With sodium chlorite; sodium dihydrogenphosphate; In water; tert-butyl alcohol; at 0 - 20 ℃; for 1h; Inert atmosphere;

upstream raw materials:

methyl (E,E)-dodeca-2,4-dienoate

(E)-3-iodoacrylic acid

(E)-undeca-1,4-diene

carbon dioxide

Downstream raw materials:

glidobactin A

Refernces

• 1、 Amatuni, Alexander,Shuster, Anton,Adibekian, Alexander,Renata, Hans. "Concise Chemoenzymatic Total Synthesis and Identification of Cellular Targets of Cepafungin I". . p. 1318 - 18,1326. Retrieved 2020/09/02.
• 2、 Ziesche, Lisa,Wolter, Laura,Wang, Hui,Brinkhoff, Thorsten,Pohlner, Marion,Engelen, Bert,Wagner-D?bler, Irene,Schulz, Stefan. "An unprecedented medium-chain diunsaturated n-acylhomoserine lactone from marine roseobacter group bacteria". . . Retrieved 2019/01/11.