Mercuric benzoate

Base Information

• Chemical Name: Mercuric benzoate
• CAS No.: 583-15-3
• Molecular Formula: C7H6 O2 . 1/2 Hg
• Molecular Weight: 442.821
• European Community (EC) Number: 209-499-1
• UN Number: 1631
• UNII: 6FAM9V1P3E
• DSSTox Substance ID: DTXSID70973838
• Nikkaji Number: J7.441A
• Mol file: 583-15-3.mol

Synonyms:MERCURIC BENZOATE;Mercury dibenzoate;583-15-3;Mercury(II) benzoate;Benzoic acid, mercury(2+) salt;beta-Mercuribenzoate;mercury(2+);dibenzoate;Mercury benzoate;HSDB 1174;EINECS 209-499-1;UN1631;UNII-6FAM9V1P3E;6FAM9V1P3E;Benzoic acid mercury(2+) salt (2:1);C7H6O2.1/2Hg;C7-H6-O2.1/2Hg;NA1631;MERCURIC BENSOATE;SCHEMBL25439;MERCURIC BENZOATE [MI];MERCURIC BENZOATE [HSDB];DTXSID70973838;Mercury benzoate [UN1631] [Poison];Mercury benzoate [UN1631] [Poison];LS-89642;Benzoic acid, mercury(2+) salt (8CI,9CI)

Chemical Property of Mercuric benzoate

Chemical Property:

• Vapor Pressure: 0.0122mmHg at 25°C
• Melting Point: 166-167 °C(lit.)
• Boiling Point: 249.3°C at 760 mmHg
• Flash Point: 111.4°C
• PSA: 52.60000
• LogP: 2.61290
• Water Solubility.: 1.2 g/100mL H2O (15°C), 2.5g/100mL H2O (100°C) [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 444.028552
• Heavy Atom Count: 19
• Complexity: 98
• Transport DOT Label: Poison

Purity/Quality:

99% ^*data from raw suppliers

MERCURIC BENZOATE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Toxic by ingestion, inhalation, and skin absorption; strong irritant. TLV: TWA 0.1 mg(Hg)/m³.
• Hazard Codes: T+,N
• Statements: 26/27/28-33-50/53
• Safety Statements: 13-28-36-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)[O-].C1=CC=C(C=C1)C(=O)[O-].[Hg+2]
• Uses: Medicine (antisyphilitic).

Technology Process of Mercuric benzoate

There total 4 articles about Mercuric benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury(I) oxide + benzoic acid (65-85-0,8013-63-6) → mercury(II) benzoate (583-15-3)

Guidance literature:

In not given; warming with concd. benzoic acid;

Reference yield:

mercury(II) diacetate (1600-27-7) + benzoic acid (65-85-0,8013-63-6) → mercury(II) benzoate (583-15-3)

Guidance literature:

In ethanol; water; in warm (ca. 50°C) aqueous ethanol (ca. 10:1 v/v), a few drops of acetic acid, cooling to 0°C;

DOI:10.1016/S0022-328X(00)80993-6

Reference yield:

benzoic acid (65-85-0,8013-63-6) + mercury(II) oxide (12653-71-3) → mercury(II) benzoate (583-15-3)

Guidance literature:

upstream raw materials:

benzoic acid

mercury(II) oxide

mercury(II) diacetate

Downstream raw materials:

benzoic acid 4-nitrophenoxycarbonyloxymethyl ester

{Ru₂(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene^(2-))}Hg(O₂CPh)2

{Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))}Hg(μ-O2CPh)2Hg(O2CPh)2

{Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))}Hg(μ-O2CC6H5)2Hg(O2CCH3)2

Refernces