Ethyl 3-oxotetradecanoate

Base Information

• Chemical Name: Ethyl 3-oxotetradecanoate
• CAS No.: 74124-22-4
• Molecular Formula: C16H30O3
• Molecular Weight: 270.412
• Mol file: 74124-22-4.mol

Synonyms:3-oxo-tetradecanoic acid ethyl ester;

Chemical Property of Ethyl 3-oxotetradecanoate

Chemical Property:

• Vapor Pressure: 0.00065mmHg at 25°C
• Refractive Index: 1.444
• Boiling Point: 309.2 °C at 760 mmHg
• PKA: 10.67±0.46(Predicted)
• Flash Point: 126.8 °C
• PSA: 43.37000
• Density: 0.922 g/cm³
• LogP: 4.42960

Purity/Quality:

97% ^*data from raw suppliers

Ethyl 3-oxotetradecanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethyl 3-oxotetradecanoate

There total 1 articles about Ethyl 3-oxotetradecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-dodecanoyl chloride (112-16-3) → tridecan-2-one (593-08-8) + ethyl 3-oxotetradecanoate (74124-22-4)

Guidance literature:

Erhitzen des Reaktionsprodukts mit Essigsaeure und wenig Schwefelsaeure;

DOI:10.1039/jr9500000322

Reference yield: 99.0%

ethyl 3-oxotetradecanoate (74124-22-4) → (R)-3-hydroxytetradecanoic acid ethyl ester (151763-75-6)

Guidance literature:

With hydrogen; Ru(II)-R-BINAP; In methanol; at 100 ℃; for 12h; under 5171.62 Torr;

Reference yield:

ethyl 3-oxotetradecanoate (74124-22-4) → tridecan-2-one (593-08-8)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In xylene; for 5h; Heating;

DOI:10.1021/jm00072a014

upstream raw materials:

n-dodecanoyl chloride

Downstream raw materials:

3-oxomyristic acid

tridecan-2-one

2-Benzhydryl-3-oxo-tetradecanoic acid ethyl ester

lauric acid