Ethyl 2-oxo-3-phenylcyclopentanecarboxylate

Base Information

Chemical Name:Ethyl 2-oxo-3-phenylcyclopentanecarboxylate
CAS No.:312312-75-7
Molecular Formula:C14H16O3
Molecular Weight:232.279
Hs Code.:2918300090
DSSTox Substance ID:DTXSID30441780
Mol file:312312-75-7.mol

Synonyms:Ethyl 2-oxo-3-phenylcyclopentanecarboxylate;312312-75-7;ethyl 2-oxo-3-phenylcyclopentane-1-carboxylate;MFCD12828195;SCHEMBL360491;DTXSID30441780;LRSQKGAKYUHQNQ-UHFFFAOYSA-N;Ethyl 2-oxo-phenylcyclopentanecarboxylate;AS-36197;Ethyl2-oxo-3-phenylcyclopentanecarboxylate;SY242305;CS-0151638;FT-0708734;InChI=1/C14H16O3/c1-2-17-14(16)12-9-8-11(13(12)15)10-6-4-3-5-7-10/h3-7,11-12H,2,8-9H2,1H

Suppliers and Price of Ethyl 2-oxo-3-phenylcyclopentanecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+%
5g
$ 2292.00

Crysdot
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+%
1g
$ 762.00

Chemenu
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95%
1g
$ 720.00

Ambeed
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+%
1g
$ 557.00

Ambeed
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+%
250mg
$ 224.00

Ambeed
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+%
100mg
$ 119.00

Alichem
Ethyl2-oxo-3-phenylcyclopentanecarboxylate
1g
$ 601.12

Alichem
Ethyl2-oxo-3-phenylcyclopentanecarboxylate
5g
$ 1819.65

AK Scientific
Ethyl2-oxo-3-phenylcyclopentanecarboxylate
1g
$ 1680.00

Activate Scientific
Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95%
1 g
$ 715.00

Total 3 raw suppliers

Chemical Property of Ethyl 2-oxo-3-phenylcyclopentanecarboxylate

Chemical Property:

Boiling Point:351.7±42.0 °C(Predicted)
PKA:11.53±0.40(Predicted)
PSA：43.37000
Density:1.141±0.06 g/cm3(Predicted)
LogP:2.31240
Storage Temp.:2-8°C
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:232.109944368
Heavy Atom Count:17
Complexity:292

Purity/Quality:

95% ^*data from raw suppliers

Ethyl2-oxo-3-phenylcyclopentanecarboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1CCC(C1=O)C2=CC=CC=C2

Technology Process of Ethyl 2-oxo-3-phenylcyclopentanecarboxylate

There total 9 articles about Ethyl 2-oxo-3-phenylcyclopentanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1924-30-7
diethyl 2-phenylhexanedioate

: 312312-75-7
ethyl 3-phenyl-2-oxocyclopentane-1-carboxylate

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; at 0 - 30 ℃; for 2h;
DOI:10.1021/acs.orglett.1c01689

Reference yield: 73.0%

: 1198-34-1
2-Phenylcyclopentanone

: 623-49-4
ethyl cyanoformate

: 312312-75-7
ethyl 3-phenyl-2-oxocyclopentane-1-carboxylate

Guidance literature:: 2-Phenylcyclopentanone; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

ethyl cyanoformate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 3h;

With water; In tetrahydrofuran; hexane;

Reference yield:

: 120-92-3
cyclopentanone

: 312312-75-7
ethyl 3-phenyl-2-oxocyclopentane-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: diethyl ether; tetrahydrofuran / 2.5 h / 0 °C / Reflux

2.1: formic acid; dihydrogen peroxide / 4 h / 20 - 40 °C

3.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexanes / 0.5 h / -78 °C

3.2: 3 h / 25 °C

With n-butyllithium; formic acid; dihydrogen peroxide; diisopropylamine; In tetrahydrofuran; hexanes; diethyl ether;