methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate

Base Information

Chemical Name:methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate
CAS No.:67776-38-9
Molecular Formula:C13H19N3O9
Molecular Weight:359.293
Hs Code.:2932990090
European Community (EC) Number:804-968-2
DSSTox Substance ID:DTXSID60381726
Nikkaji Number:J1.396.355J
Mol file:67776-38-9.mol

Synonyms:67776-38-9;methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate;METHYL 2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANURONOSYL AZIDE;Methyl 2,3,4-tetra-O-acetyl-1-azido-1-deoxy-beta-D-glucopyranuronate;SCHEMBL17819284;DTXSID60381726;PMUZMIKGOMUGFG-HHHUOAJASA-N;2-O,3-O,4-O-Triacetyl-6-O-methyl-beta-D-glucopyranuronosyl azide;Methyl (2,3,4-tetra-O-acetyl-beta-D-glucopyranosyl azide)uronate

Suppliers and Price of methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
1-Azido-1-deoxy-D-galacturonate 2,3,4-Triacetate Methyl Ester
100mg
$ 326.00

TRC
1-Azido-1-deoxy-D-glucuronate2,3,4-TriacetateMethylEster
250 mg
$ 145.00

Medical Isotopes, Inc.
Methyl2-3-4-tri-O-acetyl-β-D-glucopyranuronosylazide
100 mg
$ 395.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-acetyl-b-D-glucopyranuronosyl azide
500 mg
$ 250.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-acetyl-b-D-glucopyranuronosyl azide
250 mg
$ 150.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-acetyl-b-D-glucopyranuronosyl azide
100 mg
$ 95.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-acetyl-b-D-glucopyranuronosyl azide
1 g
$ 475.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-acetyl-b-D-glucopyranuronosyl azide
2 g
$ 900.00

American Custom Chemicals Corporation
METHYL 2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANURONOSYL AZIDE 95.00%
1G
$ 1963.50

American Custom Chemicals Corporation
METHYL 2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANURONOSYL AZIDE 95.00%
100MG
$ 750.75

Total 9 raw suppliers

Chemical Property of methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate

Chemical Property:

Melting Point:153 °C
PSA：167.34000
LogP:-0.06894
Storage Temp.:Refrigerator
Solubility.:Chloroform (Slightly), Methanol (Slightly)
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:9
Exact Mass:359.09647913
Heavy Atom Count:25
Complexity:602

Purity/Quality:

99%, ^*data from raw suppliers

1-Azido-1-deoxy-D-galacturonate 2,3,4-Triacetate Methyl Ester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OC1C(C(OC(C1OC(=O)C)N=[N+]=[N-])C(=O)OC)OC(=O)C
Isomeric SMILES:CC(=O)O[C@H]1[C@@H]([C@H](O[C@H]([C@@H]1OC(=O)C)N=[N+]=[N-])C(=O)OC)OC(=O)C
Uses 1-Azido-1-deoxy-D-galacturonate 2,3,4-Triacetate Methyl Ester could be a useful analgesic.

Technology Process of methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate

There total 14 articles about methyl (2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-azidooxane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 7355-18-2
(2S,3S,4S,5R,6S)-3,4,5,6-Tetraacetoxy-tetrahydro-pyran-2-carboxylic acid methyl ester

: 67776-38-9,163776-36-1
2,3,4-tri-O-acetyl-1-azido-1-deoxy-β-D-glucopyranuronic acid methyl ester

Guidance literature:: With trimethylsilylazide; tin(IV) chloride; In dichloromethane; for 15h;
DOI:10.1021/ol026629j

Reference yield: 92.0%

: 21085-72-3
1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester

: 67776-38-9,163776-36-1
2,3,4-tri-O-acetyl-1-azido-1-deoxy-β-D-glucopyranuronic acid methyl ester

Guidance literature:: With sodium azide; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; sodium hydrogencarbonate; at 20 ℃; for 2h;
DOI:10.1016/S0008-6215(00)00228-7

Reference yield: 82.0%

: 82228-14-6
methyl D-glucopyranuronate

: 108-24-7
acetic anhydride

: 67776-38-9,163776-36-1
2,3,4-tri-O-acetyl-1-azido-1-deoxy-β-D-glucopyranuronic acid methyl ester

Guidance literature:: methyl D-glucopyranuronate; acetic anhydride; With hydrogen bromide; In acetic acid; at 0 - 20 ℃;

With hydrogen bromide; In acetic acid; at 0 - 20 ℃;

With sodium azide; tetra(n-butyl)ammonium hydrogensulfate; sodium carbonate; In dichloromethane; at 20 ℃; for 2.5h;
DOI:10.1002/ejoc.200500646