N-ALLYLBENZAMIDE

Base Information

• Chemical Name: N-ALLYLBENZAMIDE
• CAS No.: 10283-95-1
• Molecular Formula: C10H11 N O
• Molecular Weight: 161.203
• Hs Code.: 2924299090
• Mol file: 10283-95-1.mol

Synonyms:Benzamide,N-2-propenyl- (9CI); Benzamide, N-allyl- (6CI,7CI,8CI); N-2-Propenylbenzamide;N-Allylbenzamide; NSC 205103; Phenyl-N-(2-propenyl)amide

Chemical Property of N-ALLYLBENZAMIDE

Chemical Property:

• Vapor Pressure: 0.000155mmHg at 25°C
• Melting Point: 22.5 °C
• Boiling Point: 331.5°Cat760mmHg
• PKA: 14.56±0.46(Predicted)
• Flash Point: 194°C
• PSA: 29.10000
• Density: 1.02g/cm³
• LogP: 1.99330

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-ALLYLBENZAMIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-ALLYLBENZAMIDE

There total 93 articles about N-ALLYLBENZAMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzoyl chloride (98-88-4) + 1-amino-2-propene (107-11-9,30551-89-4) → N-allylbenzamide (10283-95-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2016.11.084

Reference yield: 100.0%

1-amino-2-propene (107-11-9,30551-89-4) + benzoic acid (65-85-0,8013-63-6) → N-allylbenzamide (10283-95-1)

Guidance literature:

With 1,1'-carbonyldiimidazole; In tetrahydrofuran; at 60 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.8b03170

Reference yield: 98.0%

tert-butyl benzoyl(phenyl)carbamate (101137-69-3) + 1-amino-2-propene (107-11-9,30551-89-4) → N-allylbenzamide (10283-95-1)

Guidance literature:

With triethylamine; In dichloromethane; at 23 ℃; for 15h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.7b00429

upstream raw materials:

1-amino-2-propene

benzoic acid

N-allyl isothiocyanate

benzoyl chloride

Downstream raw materials:

(+/-)-5-methyl-1,2-diphenyl-4,5-dihydro-1H-imidazole

5-Methyl-2-phenyl-2-oxazoline

5-bromomethyl-2-phenyl-Δ²-1,3-oxazoline

N-(2,3-dibromopropyl)benzamide