N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine

Base Information

• Chemical Name: N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine
• CAS No.: 372200-88-9
• Molecular Formula: C26H32N2
• Molecular Weight: 372.55
• Mol file: 372200-88-9.mol

Synonyms:N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine;N1,N4-Bis(4-butylphenyl)benzene-1,4-diamine;1,4-BenzenediaMine, N,N'-bis(4-butylphenyl)-

Chemical Property of N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine

Chemical Property:

• Melting Point: 125-129 °C
• Boiling Point: 534.7±43.0 °C(Predicted)
• PKA: 2.58±0.50(Predicted)
• PSA: 24.06000
• Density: 1.054±0.06 g/cm3(Predicted)
• LogP: 8.00500

Purity/Quality:

97% ^*data from raw suppliers

N1,N4-Bis(4-butylphenyl)benzene-1,4-diamine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Monomer for synthesis of charge transport and light emitting polymers.

Technology Process of N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine

There total 1 articles about N,Nμ-Bis(4-butylphenyl)benzene-1,4-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

4-Butylaniline (104-13-2) + 1.4-dibromobenzene (106-37-6) → N,N'-bis(4-butylphenyl)-1,4-phenylenediamine (372200-88-9)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate; at 110 ℃; for 48h;

DOI:10.1021/ja043358u

Reference yield: 43.7%

N,N'-bis(4-butylphenyl)-1,4-phenylenediamine (372200-88-9) + 1,3-dibromobenzene (108-36-1) → C64H68N4 (1144042-78-3)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; potassium tert-butylate; In toluene; at 110 ℃; for 12h; Inert atmosphere;

DOI:10.1039/b814957g

Reference yield: 20.0%

N,N'-bis(4-butylphenyl)-1,4-phenylenediamine (372200-88-9) + para-diiodobenzene (624-38-4,1032416-46-8) → 1,4-bis(N-4'-iodophenyl-N-4''-n-butylphenylamino)benzene (851856-50-3)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate; In toluene; at 110 ℃; for 72h;

DOI:10.1021/ja043358u

upstream raw materials:

4-Butylaniline

1.4-dibromobenzene

Downstream raw materials:

1,4-bis(N-4'-iodophenyl-N-4''-n-butylphenylamino)benzene

1,4-bis(N-4'-(diphenylphosphino)phenyl,-N-4''-n-butylphenylamino)benzene

C₆₄H₆₈N₄

Refernces