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High quality 1,3-Dibromobenzene with high purity
Cas No: 108-36-1
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
108-36-1 1,3-Dibromobenzene
Cas No: 108-36-1
USD $ 40.0-50.0 / Gram 1 Gram 1000 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier
1,3-Dibromobenzene
Cas No: 108-36-1
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 500 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
1,3-dibromobenzene
Cas No: 108-36-1
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Amadis Chemical offer CAS#108-36-1;CAT#A801864
Cas No: 108-36-1
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
m-Dibromobenzene
Cas No: 108-36-1
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
1,3-Dibromobenzene
Cas No: 108-36-1
USD $ 5.0-5.0 / Kilogram 1 Kilogram 1000 Kilogram/Month Enke Pharma-tech Co.,Ltd. (Cangzhou, China ) Contact Supplier
1,3-Dibromobenzene
Cas No: 108-36-1
USD $ 2.0-2.0 / Kilogram 1 Kilogram 1-10 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
1,3-Dibromobenzene
Cas No: 108-36-1
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
1,3-Dibromobenzene-
Cas No: 108-36-1
No Data 1 Metric Ton 1 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

108-36-1 Usage

Definition

ChEBI: A dibromobenzene carrying bromo groups at positions 1 and 3.

Chemical Properties

clear colourless to light yellow liquid
InChI:InChI=1/C6H4Br2/c7-5-2-1-3-6(8)4-5/h1-4H

108-36-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A12723)  1,3-Dibromobenzene, 97+%    108-36-1 500g 9365.0CNY Detail
Alfa Aesar (A12723)  1,3-Dibromobenzene, 97+%    108-36-1 100g 2150.0CNY Detail
Alfa Aesar (A12723)  1,3-Dibromobenzene, 97+%    108-36-1 25g 718.0CNY Detail

108-36-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,3-dibromobenzene

1.2 Other means of identification

Product number -
Other names 2,6-dibromobenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Paint additives and coating additives not described by other categories
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-36-1 SDS

108-36-1Synthetic route

2,6-dibromobenzenediazonium o-benzenedisulfonimide

2,6-dibromobenzenediazonium o-benzenedisulfonimide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran for 0.333333h; Heating;92%
Multi-step reaction with 2 steps
1: 95 percent / aq. NaOH / 0.5 h / 0 - 5 °C
2: 11 percent / aq. HI; HBF4 / acetonitrile / 24 h / 60 °C
View Scheme
Multi-step reaction with 2 steps
1: 95 percent / aq. NaOH / 0.5 h / 0 - 5 °C
2: 12 percent / aq. HCl; Cu / acetonitrile / 0.25 h / 20 - 25 °C
View Scheme
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With bromine; dibromoisocyanuric acid In dichloromethane at 20℃; for 24h; UV-irradiation;92%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

(3,5-dibromophenyl)trimethyltin
17197-37-4

(3,5-dibromophenyl)trimethyltin

A

(3,5-dibromophenyl)dimethylbutyltin

(3,5-dibromophenyl)dimethylbutyltin

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

n-butyltrimethyltin
1527-99-7

n-butyltrimethyltin

D

(3-bromophenyl)trimethylstannane
17113-76-7

(3-bromophenyl)trimethylstannane

Conditions
ConditionsYield
In diethyl ether; hexane byproducts: C4H9Br; n-BuLi in hexane adding to an ether soln. of the stannane at -78°C, stirring for 30 min, hydrolyzing with 2 N HCl, org. layer sepg., drying over MgSO4; identified by gas chromy. and chromato-mass spectrometry;A 1%
B 82%
C n/a
D 13%
2,6-dibromoaniline
608-30-0

2,6-dibromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
Stage #1: 2,6-dibromoaniline With sulfuric acid; sodium nitrite In water at 0 - 5℃; for 3h;
Stage #2: With hypophosphorous acid In water at 70 - 80℃; for 3h; Reagent/catalyst; Temperature;
81%
Diazotization.Behandlung der Diazoniumsalz-Loesungen mit H3PO2 bei 5grad;
With tetrahydrofuran; n-Amyl nitrite
3-bromobenzenediazonium o-benzenedisulfonimide

3-bromobenzenediazonium o-benzenedisulfonimide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;80%
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;78%
C10H13Br2N3
401631-86-5

C10H13Br2N3

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1,3-dibromo-2-iodo-benzene
19821-80-8

1,3-dibromo-2-iodo-benzene

Conditions
ConditionsYield
With tetrafluoroboric acid; hydrogen iodide In acetonitrile at 60℃; for 24h;A 11%
B 79%
C10H13Br2N3
401631-86-5

C10H13Br2N3

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1,3-dibromo-2-chlorobenzene
19230-27-4

1,3-dibromo-2-chlorobenzene

Conditions
ConditionsYield
With hydrogenchloride; copper In acetonitrile at 20 - 25℃; for 0.25h;A 12%
B 79%
3-bromophenyl trifluoromethanesulfonate
66107-31-1

3-bromophenyl trifluoromethanesulfonate

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; triisobutylaluminum; butanone; potassium bromide In toluene at 100℃; for 24h; Inert atmosphere;78%
(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 81℃; for 8h;65%
7-(Dibrommethylen)bicyclo<2.2.1>hepta-2,5-dien

7-(Dibrommethylen)bicyclo<2.2.1>hepta-2,5-dien

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

6,6-Dibromfulven
41605-39-4

6,6-Dibromfulven

C

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
at 450℃; under 0.0001 Torr; for 4h; Title compound not separated from byproducts;A n/a
B 60%
C n/a
isophthalic acid
121-91-5

isophthalic acid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With Bromotrichloromethane; bromine; dibromoisocyanuric acid at 120℃; for 60h; Time; UV-irradiation;17%
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

cyclohexene
110-83-8

cyclohexene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

ethyl nitrite
109-95-5

ethyl nitrite

2,4-dibromo-aniline
615-57-6

2,4-dibromo-aniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

ethanol
64-17-5

ethanol

3-bromo-benzenediazonium; tribromoide

3-bromo-benzenediazonium; tribromoide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With aluminium trichloride
With aluminium trichloride
3,5-dibromoaniline
626-40-4

3,5-dibromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite
2,4-dibromo-aniline
615-57-6

2,4-dibromo-aniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With ethyl nitrite
Diazotization.Behandlung der Diazoniumsalz-Loesungen mit H3PO2 bei 5grad;
ueberfuehrung in das Diazoniumnitrat und erhitzen desselben mit Wasser;
2,6-dibromobenzaldehyde
67713-23-9

2,6-dibromobenzaldehyde

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With potassium hydroxide
Acetanilid
103-84-4

Acetanilid

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-bromoaniline
591-19-5

3-bromoaniline

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

benzene
71-43-2

benzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

Conditions
ConditionsYield
With aluminium trichloride beim Bromieren;
bromobenzene
108-86-1

bromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

C

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With hypobromous acid In 1,4-dioxane; water at 25℃; Rate constant;A 1 % Chromat.
B 64.3 % Chromat.
C 35.7 % Chromat.
1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

A

1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism; Product distribution;A 11.6 % Chromat.
B 3.2 % Chromat.
1,2,3-tribromobenzene
608-21-9

1,2,3-tribromobenzene

benzene
71-43-2

benzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

2,6-dibromo-1,1'-biphenyl
59080-32-9

2,6-dibromo-1,1'-biphenyl

C

2,3-dibromo-biphenyl

2,3-dibromo-biphenyl

D

2'-bromo-1,1':3',1'-terphenyl

2'-bromo-1,1':3',1'-terphenyl

Conditions
ConditionsYield
at 25℃; for 24h; Irradiation;A 9.5 % Chromat.
B 14.0 % Chromat.
C 12.0 % Chromat.
D 3.3 % Chromat.
1,2,4-tribromobenzene
615-54-3

1,2,4-tribromobenzene

A

bromobenzene
108-86-1

bromobenzene

B

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

D

benzene
71-43-2

benzene

E

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With potassium hydroxide; hydrogen; palladium on activated charcoal In 2,2,4-trimethylpentane at 50℃; for 0.666667h; Product distribution; var. cat.: Raney-Ni, add. of Aliquat 336;A 18 % Chromat.
B 3 % Chromat.
C 1 % Chromat.
D 42 % Chromat.
E 30 % Chromat.
Ethyl hexanoate
123-66-0

Ethyl hexanoate

1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
n-hexanoic anhydride
2051-49-2

n-hexanoic anhydride

1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
With hydrocarbon substituted imidazolidine at 20℃;
With 1,3-bis(1,1-dimethylethyl)imidazolidin-2-ylidene In 1,4-dioxane at 120℃; for 4h;
With 1,2,3,4-tetrakis(carbazol-9-yl)-5,6-dicyanobenzene; triethylamine In 1-methyl-pyrrolidin-2-one at 20℃; for 1.33333h; Inert atmosphere; Irradiation;98 %Chromat.
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

ethyl acetate
141-78-6

ethyl acetate

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

3,5-dibromoacetophenone
14401-73-1

3,5-dibromoacetophenone

C

1,1-Bis-(3,5-dibromo-phenyl)-ethanol

1,1-Bis-(3,5-dibromo-phenyl)-ethanol

D

Acetic acid 1,1-bis-(3,5-dibromo-phenyl)-ethyl ester

Acetic acid 1,1-bis-(3,5-dibromo-phenyl)-ethyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Yield given. Multistep reaction;
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

Hexanoyl chloride
142-61-0

Hexanoyl chloride

A

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

B

1-(3,5-Dibromo-phenyl)-hexan-1-one

1-(3,5-Dibromo-phenyl)-hexan-1-one

C

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

1,1-Bis-(3,5-dibromo-phenyl)-hexan-1-ol

D

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Hexanoic acid 1,1-bis-(3,5-dibromo-phenyl)-hexyl ester

Conditions
ConditionsYield
With n-butyllithium 1.) Et2O, -78 deg C, 2.) Et2O, -78 deg C; Multistep reaction;
1H-imidazole
288-32-4

1H-imidazole

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1,3-bis(1H-imidazol-1-yl)benzene
69506-91-8

1,3-bis(1H-imidazol-1-yl)benzene

Conditions
ConditionsYield
With 1-sulfanyl-2-(dimethylaminomethyl)-3-Me3Si-benzene-Cu(I); potassium carbonate In 1-methyl-pyrrolidin-2-one at 160℃; for 16h;100%
With copper(l) iodide; potassium carbonate In dimethyl sulfoxide at 150℃; for 48h;99%
With copper(l) iodide; dimethylaminoacetic acid; potassium carbonate In dimethyl sulfoxide at 110℃; for 48h; Inert atmosphere;93%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,2-dioxaborolane
196212-27-8

4,4,5,5-tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,2-dioxaborolane

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide at 90℃; for 48h; Inert atmosphere; Schlenk technique;100%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 80℃; for 16h; Inert atmosphere; Schlenk technique;96%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki-Miyaura Coupling;93%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

m-Anisidine
536-90-3

m-Anisidine

N,N'-bis(3-methoxyphenyl)-1,3-benzenediamine
202127-21-7

N,N'-bis(3-methoxyphenyl)-1,3-benzenediamine

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; bis(diphenylphosphinyl)ferrocene In toluene at 100 - 110℃; for 12h;100%
With [(π-cinnamyl)Pd(tBuXPhos)]OTf In water at 45℃; for 36h;91%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-(t-butyl)-4-methoxyphenyl boronic acid
196960-96-0

3-(t-butyl)-4-methoxyphenyl boronic acid

1,3-bis(3-tert-butyl-4-methoxyphenyl)benzene
1202392-73-1

1,3-bis(3-tert-butyl-4-methoxyphenyl)benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); barium hydroxide monohydrate In ISOPROPYLAMIDE; water at 80℃; for 48h; Suzuki-Miyaura double cross-coupling; Inert atmosphere;100%
(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

methyl iodide
74-88-4

methyl iodide

3-benzyl-8-(3-bromo-phenyl)-8-methoxy-3-aza-bicyclo[3.2.1]octane
778582-06-2

3-benzyl-8-(3-bromo-phenyl)-8-methoxy-3-aza-bicyclo[3.2.1]octane

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In hexanes; diethyl ether at -78℃; for 1h;
Stage #2: (1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one In hexanes; diethyl ether at -78℃; for 0.75h;
Stage #3: methyl iodide In tetrahydrofuran at 20℃; for 60h;
100%
(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

(1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-benzyl-8-(3-bromo-phenyl)-8-hydroxy-3-aza-bicyclo[3.2.1]octane
778581-93-4

3-benzyl-8-(3-bromo-phenyl)-8-hydroxy-3-aza-bicyclo[3.2.1]octane

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In hexanes; diethyl ether at -78℃; for 1.33333h;
Stage #2: (1R,5S)-3-benzyl-3-azabicyclo[3.2.1]octan-8-one In hexanes; diethyl ether at -78 - 20℃;
Stage #3: With ammonium chloride In water at 20℃; for 18h;
100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

5-{4,4,5,5-tetramethyl-1,3,2-(2-dioxaborolanyl)}-2-{(E)-2-phenyl-2-diphenylborylethenyl}pyridine
1160604-94-3

5-{4,4,5,5-tetramethyl-1,3,2-(2-dioxaborolanyl)}-2-{(E)-2-phenyl-2-diphenylborylethenyl}pyridine

1,3-bis[5-{(E)-2-(2-phenyl-2-diphenyl-borylethenyl)pyridyl}]benzene
1160604-69-2

1,3-bis[5-{(E)-2-(2-phenyl-2-diphenyl-borylethenyl)pyridyl}]benzene

Conditions
ConditionsYield
With sodium hydroxide; bis(tri-t-butylphosphine)palladium(0) In tetrahydrofuran; water at 60℃; for 12h; Inert atmosphere;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

C22H39BO3Si
1254941-69-9

C22H39BO3Si

C38H58O2Si2
1254941-70-2

C38H58O2Si2

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In tetrahydrofuran; water at 65℃; for 12h; Suzuki-Miyaura coupling;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

3,3''-dimethoxy-1,1':3',1''-terphenyl
171820-21-6

3,3''-dimethoxy-1,1':3',1''-terphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 80℃; for 36h; Suzuki-Miyaura Coupling; Inert atmosphere;100%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

m-phenylenediamine
108-45-2

m-phenylenediamine

Conditions
ConditionsYield
With C24H12Cu2F9N4O7; tetrabutylammomium bromide; ammonia; caesium carbonate In water at 110 - 140℃; for 16h;99%
With {(o-C6H4(NCHC6H4O)2)cobalt(II)}2; ammonia at 150℃; under 1500.15 Torr; for 10h; Autoclave; Inert atmosphere; Large scale;73%
With ammonia; water; copper(II) sulfate at 175 - 180℃;
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-trimethylstannyl-pyridine
59020-06-3

4-trimethylstannyl-pyridine

1,3-bis(4-pyridyl)benzene
170165-79-4

1,3-bis(4-pyridyl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; lithium chloride In toluene at 110℃;99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With tri-n-butyllithium magnesate complex In toluene at 0℃; for 1.5h;
Stage #2: N,N-dimethyl-formamide In toluene at 0℃; for 0.5h;
Stage #3: With citric acid at 20℃;
99%
Stage #1: 1,3-dibromobenzene With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at 0 - 5℃; for 1h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 0℃; for 1h; Further stages.;
90%
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.583333h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -78 - 20℃; for 1.5h;
63.21%
pyrrolidine
123-75-1

pyrrolidine

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1-(3-bromophenyl)-pyrrolidine
219928-13-9

1-(3-bromophenyl)-pyrrolidine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4.5h; Sealed tube;99%
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 80℃; for 4.5h; Sealed tube;99%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 80℃; for 4.5h;78%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

(3-bromophenyl)trimethylsilane
17878-47-6

(3-bromophenyl)trimethylsilane

Conditions
ConditionsYield
In water99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N-methylaniline
100-61-8

N-methylaniline

N1,N3-dimethyl-N1,N3-diphenylbenzene-1,3-diamine
308123-55-9

N1,N3-dimethyl-N1,N3-diphenylbenzene-1,3-diamine

Conditions
ConditionsYield
With (6-Dipp)PdCl2-SPhos; sodium t-butanolate In neat (no solvent) at 110℃; for 24h; Buchwald-Hartwig Coupling;99%
With potassium hexamethylsilazane In 1,4-dioxane at 100℃; for 1h; metal-free Buchwald-Hartwig amination; Inert atmosphere;96 %Chromat.
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-methoxy-3-methylbenzonitrile
53078-71-0

4-methoxy-3-methylbenzonitrile

(3-bromophenyl)(4-methoxy-3-methylphenyl)methanimine
1260433-04-2

(3-bromophenyl)(4-methoxy-3-methylphenyl)methanimine

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In diethyl ether at -78℃; for 0.5h;
Stage #2: 4-methoxy-3-methylbenzonitrile In diethyl ether at -78 - 20℃; for 2h;
Stage #3: With ammonium acetate
99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

(4-(benzyloxy)-3-methoxyphenyl)boronic acid
243990-53-6

(4-(benzyloxy)-3-methoxyphenyl)boronic acid

4,4''-bis(benzyloxy)-3,3''-dimethoxy-1,1':3',1''-terphenyl

4,4''-bis(benzyloxy)-3,3''-dimethoxy-1,1':3',1''-terphenyl

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In N,N-dimethyl-formamide at 60℃; Suzuki Coupling; Inert atmosphere;99%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

1,5-dibromo-2,4-diiodobenzene
96843-23-1

1,5-dibromo-2,4-diiodobenzene

Conditions
ConditionsYield
With sulfuric acid; iodine at 125 - 135℃; for 48h; Inert atmosphere;98.6%
With sulfuric acid; iodine at 125 - 135℃; for 6h;70%
With sulfuric acid; iodine at 130℃; for 6h; Inert atmosphere; Schlenk technique;60%
morpholine
110-91-8

morpholine

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-(3-morpholinophenyl)morpholine
51100-94-8

4-(3-morpholinophenyl)morpholine

Conditions
ConditionsYield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 24h;98%
With C30H25BrN3PPdS; potassium carbonate In iso-butanol at 100℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere;77.3%
With potassium hexamethylsilazane In 1,4-dioxane at 100℃; for 0.5h; metal-free Buchwald-Hartwig amination; Inert atmosphere;86 %Chromat.
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4,4’’-dimethoxy-1,1′:3′,1’’-terphenyl
1568-74-7

4,4’’-dimethoxy-1,1′:3′,1’’-terphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 20℃; for 4h; Suzuki-Miyaura Coupling;98%
With potassium phosphate; C17H15N4O3S(1-)*Na(1+); palladium dichloride In water at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;92%
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;90%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-bicyclo[4.2.0]octa-1,3,5-trienylboronic acid
195730-31-5

4-bicyclo[4.2.0]octa-1,3,5-trienylboronic acid

1,3-bis(benzocyclobuten-4-yl)benzene

1,3-bis(benzocyclobuten-4-yl)benzene

Conditions
ConditionsYield
With borax; tetrabutylammomium bromide; palladium dichloride In ethanol at 20℃; for 3h; Suzuki coupling;98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(3,5-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
408492-26-2

2-(3,5-dibromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; cyclopentyl methyl ether; 1,1'-di(pyridin-2-yl)-1,1',3,3'-tetrahydro-2,2'-bibenzo[d][1,3,2]diazaborole at 100℃; for 16h; Schlenk technique; Inert atmosphere;98%
Stage #1: bis(pinacol)diborane With C24H28ClIrN2O In n-heptane; isopropyl alcohol at 75℃; for 1h; Sealed tube; Inert atmosphere;
Stage #2: 1,3-dibromobenzene In n-heptane; isopropyl alcohol Sealed tube; Inert atmosphere;
98%
With 4,4'-di-tert-butyl-2,2'-bipyridine; [Ir(COD)(OMe)]2 In tetrahydrofuran at 80℃; for 16h;
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl 3-bromobenzoate
69038-74-0

tert-butyl 3-bromobenzoate

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃;
Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.;
98%
Stage #1: 1,3-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃; for 1h; Inert atmosphere;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃; for 2h; Inert atmosphere;
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

4-(difluoromethoxy)-3,5-dimethylbenzonitrile
1260433-19-9

4-(difluoromethoxy)-3,5-dimethylbenzonitrile

(3-bromophenyl)(4-(difluoromethoxy)-3,5-dimethylphenyl)methanimine
1260433-20-2

(3-bromophenyl)(4-(difluoromethoxy)-3,5-dimethylphenyl)methanimine

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In diethyl ether at -78℃; for 0.5h; Inert atmosphere;
Stage #2: 4-(difluoromethoxy)-3,5-dimethylbenzonitrile In tetrahydrofuran; diethyl ether at 0 - 20℃; for 2h;
Stage #3: With ammonium acetate In tetrahydrofuran; methanol; diethyl ether
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

3'-bromo-2-methoxybiphenyl
337535-26-9

3'-bromo-2-methoxybiphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; toluene for 24h; Suzuki reaction; Reflux; Inert atmosphere;98%
Stage #1: 1,3-dibromobenzene; 2-Methoxyphenylboronic acid With sodium carbonate In ethanol; toluene for 0.5h; Sealed tube; Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 80℃; Inert atmosphere;
57.76%
Stage #1: 1,3-dibromobenzene; 2-Methoxyphenylboronic acid With sodium carbonate In ethanol; toluene for 0.5h; Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 80℃; Sealed tube; Inert atmosphere;
57.76%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

diphenyl diselenide
1666-13-3

diphenyl diselenide

3,5-dibromophenyl phenyl selenide
1393715-73-5

3,5-dibromophenyl phenyl selenide

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; bis(pinacol)diborane; 4,4'-di-tert-butyl-2,2'-bipyridine In tetrahydrofuran at 80℃; for 24h; Inert atmosphere;
Stage #2: diphenyl diselenide With [2,2]bipyridinyl; copper(l) chloride In water; dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; regioselective reaction;
98%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N-methyl-4-(trifluoromethyl)-2-pyridinamine

N-methyl-4-(trifluoromethyl)-2-pyridinamine

1,3-bis(N-methyl-N′-(4-trifluoromethylpyridin-2-yl)amino)benzene

1,3-bis(N-methyl-N′-(4-trifluoromethylpyridin-2-yl)amino)benzene

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 130℃; for 24h; Inert atmosphere; Sealed tube;98%
4,4'-(hexafluoroisopropylidene)diphenol
1478-61-1

4,4'-(hexafluoroisopropylidene)diphenol

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

polymer, hydroxyl-terminated; monomer(s): bisphenol A6F; 1,3-dibromobenzene

polymer, hydroxyl-terminated; monomer(s): bisphenol A6F; 1,3-dibromobenzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; potassium carbonate In N,N-dimethyl-formamide; toluene at 135 - 145℃; Ullmann reaction;97%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2,4-dibromonitrobenzene
51686-78-3

2,4-dibromonitrobenzene

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 0 - 20℃; for 1.5h;97%
With sulfuric acid; nitric acid In dichloromethane at 0 - 20℃; for 0.5h;95%
With sulfuric acid; nitric acid at 20℃; for 5h;90%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene
30389-25-4

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene

C30H8F42

C30H8F42

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium acetate; palladium diacetate In tetrahydrofuran; N,N-dimethyl-formamide at 120℃; for 84h;97%

108-36-1Upstream product

108-36-1Related news

The disposition and metabolism of 1,3-Dibromobenzene (cas 108-36-1) in the rat08/19/2019

The distribution, excretion and metabolism of 1,3-dibromobenzene following a single i.p. administration to rats 100 or 300 mg/kg was investigated using radiotracer [3H] and GC-MS technique.After 72 hours about 74 to 90% were excreted in urine. The highest radioactivity was observed in the liver,...detailed

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