CBZ-DL-METHALLYLGLYCINE

Base Information

Chemical Name:CBZ-DL-METHALLYLGLYCINE
CAS No.:171881-79-1
Molecular Formula:C₁₄H₁₇NO₄
Molecular Weight:263.293
Hs Code.:
Mol file:171881-79-1.mol

Synonyms:CBZ-DL-METHALLYLGLYCINE;Cbz-2-Methallyl-glycine

Suppliers and Price of CBZ-DL-METHALLYLGLYCINE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-([(BENZYLOXY)CARBONYL]AMINO)-4-METHYLPENT-4-ENOIC ACID 95.00%
5MG
$ 503.62

Activate Scientific
Cbz-2-methallyl-glycine 95%
5 g
$ 655.00

Activate Scientific
Cbz-2-methallyl-glycine 95%
1 g
$ 236.00

Acrotein
Cbz-2-methallyl-glycine 97%
1g
$ 165.00

Acrotein
Cbz-2-methallyl-glycine 97%
0.5g
$ 110.00

Total 4 raw suppliers

Chemical Property of CBZ-DL-METHALLYLGLYCINE

Chemical Property:

Purity/Quality:

99%+, ^*data from raw suppliers

2-([(BENZYLOXY)CARBONYL]AMINO)-4-METHYLPENT-4-ENOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of CBZ-DL-METHALLYLGLYCINE

There total 5 articles about CBZ-DL-METHALLYLGLYCINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 87392-13-0,905929-81-9
(2S)-2-amino-4-methylpent-4-enoic acid

: 501-53-1,94274-21-2
benzyl chloroformate

: 171881-79-1
(S)-2-(benzyloxycarbonylamino)-4-methylpent-4-enoic acid

Guidance literature:: (2S)-2-amino-4-methylpent-4-enoic acid; With sodium hydroxide; In tetrahydrofuran; water; at 0 ℃; Inert atmosphere;

benzyl chloroformate; In tetrahydrofuran; water; at 20 ℃; Inert atmosphere;

With hydrogenchloride; In water; pH=1; Inert atmosphere;
DOI:10.1021/jo900459f

Reference yield: 65.0%

: 501-53-1,94274-21-2
benzyl chloroformate

: 200132-62-3
tert-butyl (S)-2-(diphenylmethyleneamino)-4-methylpent-4-enoate

: 171881-79-1
(S)-2-(benzyloxycarbonylamino)-4-methylpent-4-enoic acid

Guidance literature:: tert-butyl (S)-2-(diphenylmethyleneamino)-4-methylpent-4-enoate; With hydrogenchloride; In diethyl ether; water; at 20 ℃; for 18h; Inert atmosphere;

benzyl chloroformate; With sodium hydroxide; In tetrahydrofuran; water; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.9b00567

Reference yield:

: CF₃O₃S^(1-)*C₃₂H₃₇N₂O₂S⁽¹⁺⁾

: 171881-79-1
(R)-2-(benzyloxycarbonylamino)-4-methylpent-4-enoic acid

Guidance literature:: CF₃O₃S^(1-)*C₃₂H₃₇N₂O₂S⁽¹⁺⁾; With lithium triethylborohydride; In tetrahydrofuran; dichloromethane; at -78 ℃; for 1h; Inert atmosphere;

With sodium chlorite; 2-methyl-but-2-ene; water; acetic acid; In tetrahydrofuran; dichloromethane; tert-butyl alcohol; at 0 - 20 ℃; optical yield given as %ee;
DOI:10.1021/ol801657q