9-(4-Chlorophenyl)-9H-fluorene

Base Information

• Chemical Name: 9-(4-Chlorophenyl)-9H-fluorene
• CAS No.: 21846-07-1
• Molecular Formula: C19H13Cl
• Molecular Weight: 276.765
• DSSTox Substance ID: DTXSID20176251
• Nikkaji Number: J1.610.084F
• Wikidata: Q83046576
• Mol file: 21846-07-1.mol

Synonyms:9-(4-CHLOROPHENYL)-9H-FLUORENE;21846-07-1;DTXSID20176251

Chemical Property of 9-(4-Chlorophenyl)-9H-fluorene

Chemical Property:

• Vapor Pressure: 2.23E-06mmHg at 25°C
• Boiling Point: 404.3°Cat760mmHg
• Flash Point: 185.1°C
• Density: 1.232g/cm³
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 276.0705781
• Heavy Atom Count: 20
• Complexity: 309

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(C3=CC=CC=C32)C4=CC=C(C=C4)Cl

Technology Process of 9-(4-Chlorophenyl)-9H-fluorene

There total 17 articles about 9-(4-Chlorophenyl)-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

α-(4'-chlorophenyl)biphenyl-2-methanol (113769-85-0) → 9-(4-chlorophenyl)-9H-fluorene (21846-07-1)

Guidance literature:

With iron(III) chloride; In nitromethane; at 20 ℃; for 0.0833333h;

DOI:10.1016/j.tetlet.2012.08.005

Reference yield: 90.0%

acetic acid (biphenyl-2-yl)(4-chlorophenyl)methyl ester (1065544-28-6) → 9-(4-chlorophenyl)-9H-fluorene (21846-07-1)

Guidance literature:

With trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 0.0166667h;

DOI:10.1016/j.tet.2008.07.021

Reference yield: 89.0%

bromochlorobenzene (106-39-8) + 9H-fluoren-9-yllithium (881-04-9) → 9-(4-chlorophenyl)-9H-fluorene (21846-07-1)

Guidance literature:

With bis(tri-t-butylphosphine)palladium⁽⁰⁾; In toluene; at 20 ℃; for 1h;

DOI:10.1039/c3sc53047g

upstream raw materials:

α-(4'-chlorophenyl)biphenyl-2-methanol

1-(biphenyl-2'-yl)-1-(4-chlorophenyl)but-3-en-1-ol

2-Phenylbenzaldehyde

4-chlorophenylmagnesium iodide