113769-85-0

Basic information

• Product Name: α-(4'-chlorophenyl)biphenyl-2-methanol
• Synonyms: α-(4'-chlorophenyl)biphenyl-2-methanol
• CAS NO: 113769-85-0
• Molecular Weight: 294.78
• Mol File: 113769-85-0.mol

Chemical Properties

• CAS DataBase Reference: α-(4'-chlorophenyl)biphenyl-2-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: α-(4'-chlorophenyl)biphenyl-2-methanol(113769-85-0)
• EPA Substance Registry System: α-(4'-chlorophenyl)biphenyl-2-methanol(113769-85-0)

Safety Data

• Hazardous Substances Data: 113769-85-0(Hazardous Substances Data)

Upstream product

• 1203-68-5 2-Phenylbenzaldehyde 
• 7270-47-5 4-chlorophenylmagnesium iodide 
• 106-39-8 bromochlorobenzene 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 108-90-7 chlorobenzene 
• 947-84-2 2-Biphenylcarboxylic acid 
• 2928-43-0 2-biphenylmethanol 

Downstream Products

• 21846-07-1 9-(4-chlorophenyl)-9H-fluorene 
• 113449-33-5 (biphenyl-2-yl)(4'-chlorophenyl)methanone 
• 98351-80-5 6-(4′-chlorophenyl)phenanthridine 
• 1065544-28-6 acetic acid (biphenyl-2-yl)(4-chlorophenyl)methyl ester 
• 113769-86-1 1-(biphenyl-2'-yl)-1-(4-chlorophenyl)but-3-en-1-ol 
• 37842-69-6 9-(4'-chlorophenyl)phenanthrene 

Relevant articles and documents

6-Arylphenanthridines from Aryl o-Biaryl Ketones with 1,1,1,3,3,3-Hexamethyldisilazane and Molecular Iodine

Warming treatment of aryl o-biaryl ketones with 1,1,1,3,3,3-hexamethyldisilazane in the presence of Sc(OTf)3 in toluene, followed by the reaction with molecular iodine and K2CO3 in a mixture of THF and methanol at 60 °C gave the corresponding 6-arylphenanthridines in good to moderate yields. The present reaction is a one-pot method for the preparation of 6-arylphenanthridines from aryl o-biaryl ketones through the cyclization of imino-nitrogen-centered radicals that were generated from N-iodo aryl o-biaryl ketimines formed from the reaction of aryl biaryl ketimines with molecular iodine.

Highly efficient synthesis of polysubstituted fluorene via iron-catalyzed intramolecular Friedel-Crafts alkylation of biaryl alcohols

An efficient and mild Fe(III)-catalyzed intramolecular Friedel-Crafts alkylation of biaryl methanol derivatives has been developed to achieve the substituted fluorene derivatives. The present reaction provides an excellent alternative to published methods

A general and efficient synthesis of substituted fluorenes and heterocycle-fused indenes containing thiophene or indole rings utilizing a Suzuki-Miyaura coupling and acid-catalyzed Friedel-Crafts reactions as key steps

A general and efficient synthesis of fluorenes or heterocycle-fused indenes including 3-thia-cyclopenta[a]indenes, 9-thia-indeno[1,2-a]indenes, 5,6-dihydroindeno[2,1-b]indoles has been developed. This methodology is realized by a multistep protocol involv

Synthesis of 4-(4'-Chlorophenyl)-5-phenyl-1,2-dihydronaphthalene

BF3-catalysed cyclization reactions of 1-(biphenyl-2'-yl)-1-(4"-chlorophenyl)but-3-en-1-ol yielded none of the desired title compound but only 9-(4'-chlorophenyl)-10-ethylphenanthrene and 9-allyl-9-(4'-chlorophenyl)fluorene by alternative cyclization path