(Z)-hexadec-2-enoic acid

Base Information

Chemical Name:(Z)-hexadec-2-enoic acid
CAS No.:2825-68-5
Molecular Formula:C16H30O2
Molecular Weight:254.413
Hs Code.:
DSSTox Substance ID:DTXSID601313402
Nikkaji Number:J1.511.278F
Metabolomics Workbench ID:685
Mol file:2825-68-5.mol

Synonyms:cis-hexadecenoic acid;hexadecenoic acid;hexadecenoic acid, (E)-isomer;hexadecenoic acid, (Z)-isomer;trans-hexadecenoic acid

Suppliers and Price of (Z)-hexadec-2-enoic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Cayman Chemical
Δ2-cis-Hexadecenoic Acid ≥98%
10mg
$ 343.00

Cayman Chemical
Δ2-cis-Hexadecenoic Acid ≥98%
5mg
$ 196.00

Cayman Chemical
Δ2-cis-Hexadecenoic Acid
1mg
$ 49.00

AK Scientific
2Z-Hexadecenoicacid
10mg
$ 563.00

Total 8 raw suppliers

Chemical Property of (Z)-hexadec-2-enoic acid

Chemical Property:

PSA：37.30000
LogP:5.32830
XLogP3:7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:13
Exact Mass:254.224580195
Heavy Atom Count:18
Complexity:209

Purity/Quality:

99% ^*data from raw suppliers

Δ2-cis-Hexadecenoic Acid ≥98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCCCCCCCC=CC(=O)O
Isomeric SMILES:CCCCCCCCCCCCC/C=C\C(=O)O

Technology Process of (Z)-hexadec-2-enoic acid

There total 8 articles about (Z)-hexadec-2-enoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2834-03-9
2-hexadecynoic acid

: 2825-68-5
cis-Hexadec-2-enoic acid

Guidance literature:: With quinoline; hydrogen; In hexane; for 8h;
DOI:10.1021/acs.orglett.8b02832

Reference yield:

: 112-72-1
1-Tetradecanol

: 2825-68-5
cis-Hexadec-2-enoic acid

Guidance literature:: Multi-step reaction with 5 steps

1.1: pyridine; chromium(VI) oxide; silica gel / dichloromethane / 1.5 h / Inert atmosphere

2.1: triphenylphosphine / dichloromethane / 0.08 h / -5 °C / Inert atmosphere

2.2: 2.5 h / -5 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere

3.2: 8 h / 20 °C / Inert atmosphere

4.1: lithium hydroxide / tetrahydrofuran; water / 6 h / 40 °C / Inert atmosphere

5.1: quinoline; hydrogen / hexane / 8 h

With pyridine; quinoline; chromium(VI) oxide; n-butyllithium; hydrogen; silica gel; triphenylphosphine; lithium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1021/acs.orglett.8b02832

Reference yield:

: 124-25-4,511542-15-7
myristylaldehyde

: 2825-68-5
cis-Hexadec-2-enoic acid

Guidance literature:: Multi-step reaction with 4 steps

1.1: triphenylphosphine / dichloromethane / 0.08 h / -5 °C / Inert atmosphere

1.2: 2.5 h / -5 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere

2.2: 8 h / 20 °C / Inert atmosphere

3.1: lithium hydroxide / tetrahydrofuran; water / 6 h / 40 °C / Inert atmosphere

4.1: quinoline; hydrogen / hexane / 8 h

With quinoline; n-butyllithium; hydrogen; triphenylphosphine; lithium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1021/acs.orglett.8b02832