2,4-DICHLOROBENZYLZINC CHLORIDE

Base Information

• Chemical Name: 2,4-DICHLOROBENZYLZINC CHLORIDE
• CAS No.: 737797-16-9
• Molecular Formula: C₇H₅Cl₃Zn
• Molecular Weight: 260.866
• Mol file: 737797-16-9.mol

Synonyms:2,4-DICHLOROBENZYLZINC CHLORIDE

Chemical Property of 2,4-DICHLOROBENZYLZINC CHLORIDE

Chemical Property:

• PSA: 0.00000
• LogP: 3.99610

Purity/Quality:

97% ^*data from raw suppliers

2,4-DICHLOROBENZYLZINC CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-DICHLOROBENZYLZINC CHLORIDE

There total 1 articles about 2,4-DICHLOROBENZYLZINC CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-Dichlorobenzyl chloride (94-99-5) + zinc (7440-66-6) → C7H5Cl3Zn (737797-16-9)

Guidance literature:

With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; In tetrahydrofuran; at 70 ℃; for 1h; Inert atmosphere; Microwave irradiation;

DOI:10.1055/s-0034-1379458

Reference yield: 50.0%

3-ethoxy-4-iodo-1H-pyrazole (1207431-89-7) + C7H5Cl3Zn (737797-16-9) → 4-(2,4-dichlorobenzyl)-3-ethoxy-1H-pyrazole

Guidance literature:

With palladium diacetate; XPhos; In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere; Microwave irradiation;

DOI:10.1055/s-0034-1379458

Reference yield:

3-ethoxy-4-iodo-1H-pyrazole (1207431-89-7) + C7H5Cl3Zn (737797-16-9) → 4-(2,4-dichlorobenzyl)-3-ethoxy-5-iodo-1H-pyrazole

Guidance literature:

Multi-step reaction with 2 steps

1: palladium diacetate; XPhos / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere; Microwave irradiation

2: N-iodo-succinimide / 1,2-dichloro-ethane / 10 h / Reflux

With N-iodo-succinimide; palladium diacetate; XPhos; In tetrahydrofuran; 1,2-dichloro-ethane; 1: |Negishi Coupling;

DOI:10.1055/s-0034-1379458

upstream raw materials:

2,4-Dichlorobenzyl chloride

zinc

Refernces