4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid

Base Information

Chemical Name:4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid
CAS No.:69842-14-4
Molecular Formula:C₁₁H₁₄O₄
Molecular Weight:210.23
Hs Code.:
DSSTox Substance ID:DTXSID10377876
Mol file:69842-14-4.mol

Synonyms:69842-14-4;4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylic acid;4,7,7-TRIMETHYL-2,3-DIOXOBICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID;camphorquinone carboxylic acid;SCHEMBL147335;DTXSID10377876;STL553114;AKOS000267984;AKOS016038843;EN300-236308;F1052-0004;4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylicacid

Suppliers and Price of 4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylicAcid
10mg
$ 45.00

Matrix Scientific
4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylic acid 95%+
1g
$ 479.00

Matrix Scientific
4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylic acid 95%+
5g
$ 1584.00

Matrix Scientific
4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylic acid 95%+
2.500g
$ 1048.00

American Custom Chemicals Corporation
4,7,7-TRIMETHYL-2,3-DIOXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID 95.00%
5MG
$ 499.31

Total 5 raw suppliers

Chemical Property of 4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid

Chemical Property:

PSA：71.44000
LogP:1.03550
XLogP3:1.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:210.08920892
Heavy Atom Count:15
Complexity:395

Purity/Quality:

97% ^*data from raw suppliers

4,7,7-Trimethyl-2,3-dioxo-bicyclo[2.2.1]heptane-1-carboxylicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2(CCC1(C(=O)C2=O)C(=O)O)C)C

Technology Process of 4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid

There total 8 articles about 4,7,7-Trimethyl-2,3-dioxobicyclo[2.2.1]heptane-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10309-20-3
3,3-dimethyl-2-methylene-norbornane-1-carboxylic acid

: 69842-14-4
4,7,7-trimethyl-2,3-dioxo-norbornane-1-carboxylic acid

Guidance literature:: Multi-step reaction with 6 steps

1: sulfuric acid / 80 °C

2: diluted NaOH-solution

3: natrium carbonatalkaline permanganate

4: sulfuric acid

5: sodium amide; benzene / nachf. Behandeln mit Isoamylnitrit

6: glacial acetic acid; NaHSO₃ / Versetzen mit verd. Salzsaeure

With sodium hydroxide; natrium carbonatalkaline permanganate; sulfuric acid; sodium amide; sodium hydrogensulfite; acetic acid; benzene;

Reference yield:

: 2-hydroxyimino-4,7,7-trimethyl-3-oxo-norbornane-1-carboxylic acid

: 69842-14-4
4,7,7-trimethyl-2,3-dioxo-norbornane-1-carboxylic acid

Guidance literature:: With sodium hydrogensulfite; acetic acid; Versetzen mit verd. Salzsaeure;

Reference yield:

: 93257-31-9
3-hydroxy-4,7,7-trimethyl-norbornane-1-carboxylic acid

: 69842-14-4
4,7,7-trimethyl-2,3-dioxo-norbornane-1-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: natrium carbonatalkaline permanganate

2: sulfuric acid

3: sodium amide; benzene / nachf. Behandeln mit Isoamylnitrit

4: glacial acetic acid; NaHSO₃ / Versetzen mit verd. Salzsaeure

With natrium carbonatalkaline permanganate; sulfuric acid; sodium amide; sodium hydrogensulfite; acetic acid; benzene;