2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl

Base Information

Chemical Name:2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl
CAS No.:38582-80-8
Deprecated CAS:41797-72-2
Molecular Formula:C₁₁H₂₁N₂O₂
Molecular Weight:213.3
Hs Code.:
DSSTox Substance ID:DTXSID20191904
Mol file:38582-80-8.mol

Synonyms:2-TBTIOO;2-tert-butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl

Suppliers and Price of 2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl

Chemical Property:

PSA：31.99000
LogP:2.05630
XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:213.160302917
Heavy Atom Count:15
Complexity:286

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C([N+](=C(N1[O])C(C)(C)C)[O-])(C)C)C

Technology Process of 2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl

There total 4 articles about 2-tert-Butyl-4,4,5,5-tetramethylimidazoline-3-oxide 1-oxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 351902-08-4
2-tert-butyl-4,4,5,5-tetramethyl-imidazolidine

: 38582-80-8,41797-72-2
2-tert-butyl-4,4,5,5-tetramethyl-3-oxy-4,5-dihydro-imidazol-1-yloxyl

Guidance literature:: 2-tert-butyl-4,4,5,5-tetramethyl-imidazolidine; With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 1h; Ice cooling;

With sodium periodate; In dichloromethane; Further stages.;
DOI:10.1002/1521-3765(20010504)7:9<2007::AID-CHEM2007>3.0.CO;2-7

Reference yield:

: 20485-44-3
2,3-dimethyl-2,3-diaminobutane

: 38582-80-8,41797-72-2
2-tert-butyl-4,4,5,5-tetramethyl-3-oxy-4,5-dihydro-imidazol-1-yloxyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: 95 percent / diethyl ether / ice cooling

2.1: m-chloroperbenzoic acid; NaHCO₃ / CH₂Cl₂ / 1 h / Ice cooling

2.2: aq. NaIO₄ / CH₂Cl₂

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane;
DOI:10.1002/1521-3765(20010504)7:9<2007::AID-CHEM2007>3.0.CO;2-7

Reference yield:

: 3964-18-9
2,3-dimethyl-2,3-dinitrobutane

: 38582-80-8,41797-72-2
2-tert-butyl-4,4,5,5-tetramethyl-3-oxy-4,5-dihydro-imidazol-1-yloxyl

Guidance literature:: Multi-step reaction with 3 steps

1.1: 81 percent / Sn; aq. HCl / 3 h / Heating

2.1: 95 percent / diethyl ether / ice cooling

3.1: m-chloroperbenzoic acid; NaHCO₃ / CH₂Cl₂ / 1 h / Ice cooling

3.2: aq. NaIO₄ / CH₂Cl₂

With hydrogenchloride; tin; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane;
DOI:10.1002/1521-3765(20010504)7:9<2007::AID-CHEM2007>3.0.CO;2-7