4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester

Base Information

Chemical Name:4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester
CAS No.:909247-46-7
Molecular Formula:C17H17NO7S
Molecular Weight:379.39
Hs Code.:
DSSTox Substance ID:DTXSID50468252
Wikidata:Q82295397
Mol file:909247-46-7.mol

Synonyms:909247-46-7;4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester;Dimethyl 4-[(4-methylphenyl)sulfonyloxymethyl]pyridine-2,6-dicarboxylate;AGN-PC-00B56O;SCHEMBL21189125;DTXSID50468252;FT-0672181

Suppliers and Price of 4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylicAcid2,6-DimethylEster
100mg
$ 580.00

American Custom Chemicals Corporation
4-[[[(4-METHYLPHENYL)SULFONYL]OXY]METHYL]-2,6-PYRIDINEDICARBOXYLIC ACID-2,6-DIMETHYL ESTER 95.00%
5MG
$ 499.61

Total 1 raw suppliers

Chemical Property of 4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester

Chemical Property:

PSA：117.24000
LogP:2.94950
Solubility.:Dichloromethane
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:8
Exact Mass:379.07257305
Heavy Atom Count:26
Complexity:569

Purity/Quality:

97% ^*data from raw suppliers

4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylicAcid2,6-DimethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2=CC(=NC(=C2)C(=O)OC)C(=O)OC
Uses 4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester (cas# 909247-46-7) is a compound useful in organic synthesis.

Technology Process of 4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester

There total 3 articles about 4-[[[(4-Methylphenyl)sulfonyl]oxy]methyl]-2,6-pyridinedicarboxylic Acid 2,6-Dimethyl Ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 852936-60-8
dimethyl 4-(hydroxylmethyl)pyridine-2,6-dicarboxylate

: 98-59-9
p-toluenesulfonyl chloride

: 909247-46-7
dimethyl 4-tosyloxymethylpyridine-2,6-dicarboxylate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 1.5h;
DOI:10.1080/00397910600634381

Reference yield:

: 5453-67-8
2,6-bis(methoxycarbonyl)pyridine

: 909247-46-7
dimethyl 4-tosyloxymethylpyridine-2,6-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 41 percent / FeSO₄*7H₂₀; H₂O₂; H₂SO₄ / H₂O / 15 - 30 °C

2: 81 percent / triethylamine / CH₂Cl₂ / 1.5 h / 0 - 20 °C

With sulfuric acid; dihydrogen peroxide; iron(II) sulfate; triethylamine; In dichloromethane; water;
DOI:10.1080/00397910600634381

Reference yield:

: 499-83-2
Pyridine-2,6-dicarboxylic acid

: 909247-46-7
dimethyl 4-tosyloxymethylpyridine-2,6-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: CH₃COCl

2: 41 percent / FeSO₄*7H₂₀; H₂O₂; H₂SO₄ / H₂O / 15 - 30 °C

3: 81 percent / triethylamine / CH₂Cl₂ / 1.5 h / 0 - 20 °C

With sulfuric acid; dihydrogen peroxide; iron(II) sulfate; triethylamine; acetyl chloride; In dichloromethane; water;
DOI:10.1080/00397910600634381