1,2,4,5-Tetrakis(dimethylsilyl)benzene

Base Information

Chemical Name:1,2,4,5-Tetrakis(dimethylsilyl)benzene
CAS No.:10095-29-1
Molecular Formula:C14H30Si4
Molecular Weight:310.734
Hs Code.:
European Community (EC) Number:660-075-6
Nikkaji Number:J677.149A
Mol file:10095-29-1.mol

Synonyms:1,2,4,5-Tetrakis(dimethylsilyl)benzene;AKOS024338600;dimethyl[2,4,5-tris(dimethylsilyl)phenyl]silane;10095-29-1

Suppliers and Price of 1,2,4,5-Tetrakis(dimethylsilyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
1,2,4,5-BENZENETETRAYLTETRAKIS(DIMETHYLSILANE) Aldrich
1ea
$ 144.00

Total 0 raw suppliers

Chemical Property of 1,2,4,5-Tetrakis(dimethylsilyl)benzene

Chemical Property:

PSA：0.00000
LogP:0.46140
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:310.14245709
Heavy Atom Count:18
Complexity:200

Purity/Quality:: 1,2,4,5-BENZENETETRAYLTETRAKIS(DIMETHYLSILANE) Aldrich ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[SiH](C)C1=CC(=C(C=C1[SiH](C)C)[SiH](C)C)[SiH](C)C

Technology Process of 1,2,4,5-Tetrakis(dimethylsilyl)benzene

There total 2 articles about 1,2,4,5-Tetrakis(dimethylsilyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 636-28-2
1,2,4,5-tetrabromobenzene

: 1066-35-9
dimethylmonochlorosilane

: 10095-29-1
1,2,4,5-tetrakis(dimethylsilyl)benzene

Guidance literature:: With magnesium; In tetrahydrofuran; Heating;
DOI:10.1016/S0040-4039(02)00239-3

Reference yield:

: 10095-29-1
1,2,4,5-tetrakis(dimethylsilyl)benzene

Guidance literature:: Tetrabrombenzol, BrMgSiH(CH3)2;
DOI:10.1002/hlca.19740570407

Reference yield:

: 10095-29-1
1,2,4,5-tetrakis(dimethylsilyl)benzene

: N-benzoyl-1,3,5,6,7,8-hexahydro-1,1,3,3-tetramethyl-5,8-iminenaphth[2,3-c][1,2,5]oxadisilole

Guidance literature:: Multi-step reaction with 3 steps

1.1: MeONa / methanol / 1 h / 20 °C

1.2: 87 percent / H₂O / methanol / 45 - 50 °C

2.1: trifluoromethanesulfonic acid; PhI(OAc)2 / CH₂Cl₂ / 0 - 20 °C

2.2: 78 percent / iPr₂NH; n-Bu₄NF / CH₂Cl₂; tetrahydrofuran / 0.17 h / 20 °C

3.1: 85 percent / H₂ / Pd/C / ethanol / 2 h / 20 °C

With trifluorormethanesulfonic acid; [bis(acetoxy)iodo]benzene; hydrogen; sodium methylate; palladium on activated charcoal; In methanol; ethanol; dichloromethane;
DOI:10.1021/jo049091z