Ethyl 8-(4-bromophenyl)-8-oxooctanoate

Base Information

Chemical Name:Ethyl 8-(4-bromophenyl)-8-oxooctanoate
CAS No.:362669-43-0
Molecular Formula:C16H21BrO3
Molecular Weight:341.24
Hs Code.:2918300090
DSSTox Substance ID:DTXSID80452346
Nikkaji Number:J2.043.753G
Wikidata:Q82272918
Mol file:362669-43-0.mol

Synonyms:ETHYL 8-(4-BROMOPHENYL)-8-OXOOCTANOATE;362669-43-0;MFCD01320180;Ethyl 7-(4-bromobenzoyl)heptanoate;SCHEMBL3382103;DTXSID80452346;ROAGOUNIEVPAAN-UHFFFAOYSA-N;AKOS016022632;ETHYL8-(4-BROMOPHENYL)-8-OXOOCTANOATE;8-Oxo-8-(4-bromophenyl)octanoic acid ethyl ester

Suppliers and Price of Ethyl 8-(4-bromophenyl)-8-oxooctanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
Ethyl8-(4-bromophenyl)-8-oxooctanoate 97%
1g
$ 303.00

Rieke Metals
Ethyl8-(4-bromophenyl)-8-oxooctanoate 97%
2g
$ 529.00

Rieke Metals
Ethyl8-(4-bromophenyl)-8-oxooctanoate 97%
5g
$ 1250.00

Matrix Scientific
Ethyl 8-(4-bromophenyl)-8-oxooctanoate
5g
$ 1165.00

Matrix Scientific
Ethyl 8-(4-bromophenyl)-8-oxooctanoate
2g
$ 525.00

Matrix Scientific
Ethyl 8-(4-bromophenyl)-8-oxooctanoate
1g
$ 319.00

Crysdot
Ethyl8-(4-bromophenyl)-8-oxooctanoate 95+%
1g
$ 316.00

Crysdot
Ethyl8-(4-bromophenyl)-8-oxooctanoate 95+%
5g
$ 1156.00

American Custom Chemicals Corporation
ETHYL 8-(4-BROMOPHENYL)-8-OXOOCTANOATE 95.00%
10G
$ 2789.33

American Custom Chemicals Corporation
ETHYL 8-(4-BROMOPHENYL)-8-OXOOCTANOATE 95.00%
5G
$ 1988.91

Total 2 raw suppliers

Chemical Property of Ethyl 8-(4-bromophenyl)-8-oxooctanoate

Chemical Property:

Vapor Pressure:2.83E-07mmHg at 25°C
Boiling Point:420.4°C at 760 mmHg
Flash Point:208°C
PSA：43.37000
Density:1.251g/cm³
LogP:4.53550
XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:10
Exact Mass:340.06741
Heavy Atom Count:20
Complexity:296

Purity/Quality:

97% ^*data from raw suppliers

Ethyl8-(4-bromophenyl)-8-oxooctanoate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)CCCCCCC(=O)C1=CC=C(C=C1)Br

Technology Process of Ethyl 8-(4-bromophenyl)-8-oxooctanoate

There total 3 articles about Ethyl 8-(4-bromophenyl)-8-oxooctanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 51100-70-0
ethyl 7-iodoheptanoate

: 586-75-4
4-chlorobenzoyl chloride

: 362669-43-0
ethyl 7-(4-bromobenzoyl)heptanoate

Guidance literature:: ethyl 7-iodoheptanoate; With chloro-trimethyl-silane; ethylene dibromide; zinc;

With lithium chloride; In tetrahydrofuran;

4-chlorobenzoyl chloride; In tetrahydrofuran;
DOI:10.1016/j.bmcl.2003.08.083

Reference yield: 70.0%

: 586-75-4
4-chlorobenzoyl chloride

: 103187-95-7
ethyl 8-oxo-8-phenyloctanoate

: 362669-43-0
ethyl 7-(4-bromobenzoyl)heptanoate

Guidance literature:

Reference yield:

: 29823-18-5
ethyl 7-bromoheptanoate

: 362669-43-0
ethyl 7-(4-bromobenzoyl)heptanoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 83 percent / NaI / acetone / Heating

2.1: Zn; (CH₂)Br₂; TMSCl / tetrahydrofuran / 16 h / 20 - 60 °C

2.2: CuCN; LiCl / tetrahydrofuran / 0.17 h / 0 °C

2.3: tetrahydrofuran / 3 h / 0 °C

With chloro-trimethyl-silane; sodium iodide; zinc; 1,1-dibromomethane; In tetrahydrofuran; acetone;
DOI:10.1021/jm020154k