2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Base Information

Chemical Name:2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate
CAS No.:1449472-59-6
Molecular Formula:C₁₀H₁₂ClF₃O₃SSi
Molecular Weight:332.803
Hs Code.:
Mol file:1449472-59-6.mol

Synonyms:2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate;2-Chloro-6-(trimethylsilyl)phenyl triflate 95%

Suppliers and Price of 2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of 2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

There total 2 articles about 2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 72525-60-1
hexamethyldisilazan

: 358-23-6
trifluoromethylsulfonic anhydride

: 2040-88-2
2-bromo-6-chlorophenol

: 1449472-59-6
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Guidance literature:: hexamethyldisilazan; 2-bromo-6-chlorophenol; In tetrahydrofuran; Reflux;

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.333333h; Inert atmosphere;

trifluoromethylsulfonic anhydride; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1021/jacs.1c04389

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: C₉H₁₂BrClOSi

: 1449472-59-6
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Guidance literature:: C₉H₁₂BrClOSi; With n-butyllithium; In tetrahydrofuran; at -100 - -80 ℃; for 0.5h;

trifluoromethylsulfonic anhydride; In tetrahydrofuran; at -100 - 20 ℃; for 2.5h;
DOI:10.1039/c3cc44529a

Reference yield: 92.0%

: 1449472-59-6
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 73183-34-3
bis(pinacol)diborane

: 2-chloro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6-(trimethylsilyl)phenyl triflate

Guidance literature:: bis(pinacol)diborane; With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In hexane; at 20 ℃; for 0.166667h; Inert atmosphere;

2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate; In hexane; at 20 ℃; for 22h; Inert atmosphere;
DOI:10.1246/cl.190223