Asarylaldehyde

Base Information

• Chemical Name: Asarylaldehyde
• CAS No.: 14374-62-0
• Molecular Formula: C₁₀H₁₂O₄
• Molecular Weight: 196.203
• Mol file: 14374-62-0.mol

Synonyms:Asaronaldehyde;Azarylaldehyde;Asarylaldehyde;Gazarin;3,4,6-Trimethoxybenzaldehyde;Asaraldehyde;Benzaldehyde,2,4,5-trimethoxy;

Chemical Property of Asarylaldehyde

Chemical Property:

• Melting Point: 114oC
• PSA: 44.76000
• LogP: 1.52490

Purity/Quality:

98% Min ^*data from raw suppliers

Asarylaldehyde ≥98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Asarylaldehyde

There total 44 articles about Asarylaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

difluoromethyl phenyl sulfide (1535-67-7) + 1,2,4-trimethoxy-benzene (135-77-3) → asaraldehyde (4460-86-0,14374-62-0)

Guidance literature:

difluoromethyl phenyl sulfide; 1,2,4-trimethoxy-benzene; With tin(IV) chloride; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;

With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dichloromethane; water; dimethyl sulfoxide; at 20 ℃; for 2h;

DOI:10.1055/s-0036-1591545

Reference yield: 97.0%

(2,4,5-trimethoxyphenyl)methanol (30038-31-4) → asaraldehyde (4460-86-0,14374-62-0)

Guidance literature:

With copper(l) iodide; TEMPOL; N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine; In acetonitrile; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/S1872-2067(14)60161-3

Reference yield: 84.0%

α-asarone (2883-98-9) → asaraldehyde (4460-86-0,14374-62-0)

Guidance literature:

With sodium periodate; osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; In tetrahydrofuran; water; microwave irradiation;

DOI:10.1246/cl.2003.780

upstream raw materials:

hydrogen cyanide

1,2,4-trimethoxy-benzene

asarone

2,4,5-trimethoxycinnamic acid

Downstream raw materials:

5-(2,4,5-trimethoxy-benzylidene)-imidazolidine-2,4-dione

2-thioxo-5-(2,4,5-trimethoxy-benzylidene)-thiazolidin-4-one

5t-(2,4,5-trimethoxy-phenyl)-penta-2t,4-dienoic acid methyl ester

2-cyano-3-(2,4,5-trimethoxy-phenyl)-acrylic acid ethyl ester