PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method]

Base Information

• Chemical Name: PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method]
• CAS No.: 210769-64-5
• Molecular Formula: C95H64N8O4Zn2
• Molecular Weight: 1512.35586
• Mol file: 210769-64-5.mol

Synonyms:PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method]

Chemical Property of PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method]

Chemical Property:

• PSA: 98.20000
• LogP: 13.36810
• Storage Temp.: 0-10°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Pentamethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality method] >97.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method]

There total 3 articles about PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1 ,5-pentanediol (111-29-5) + 5-(4-carboxyphenyl)-10,15,20-triphenyl-21H,23H-porphyrin (95051-10-8) + zinc diacetate (557-34-6) → pentamethylene bis[4-(10,15,20-triphenylporphin-5-yl)benzoate]dizinc(II) (210769-64-5)

Guidance literature:

In not given; coupling of diol with porphyrin, followed by Zn-insertion;

DOI:10.1021/ja973539e

Reference yield:

zinc(II) chloride (7646-85-7,24359-56-6) → pentamethylene bis[4-(10,15,20-triphenylporphin-5-yl)benzoate]dizinc(II) (210769-64-5)

Guidance literature:

In pyridine; refluxing porphyrin deriv. with zinc compd. in pyridine;

DOI:10.1002/anie.200503316

Reference yield:

C95H68N8O4 → pentamethylene bis[4-(10,15,20-triphenylporphin-5-yl)benzoate]dizinc(II) (210769-64-5)

Guidance literature:

With zinc diacetate; In dichloromethane;

DOI:10.1002/ejoc.201200147

upstream raw materials:

1 ,5-pentanediol

5-(4-carboxyphenyl)-10,15,20-triphenyl-21H,23H-porphyrin

zinc diacetate

zinc(II) chloride

Downstream raw materials:

C₆H₁₆N₂*C₉₅H₆₄N₈O₄Zn₂

C₅H₁₄N₂*C₉₅H₆₄N₈O₄Zn₂

C₇H₁₈N₂*C₉₅H₆₄N₈O₄Zn₂

C₈H₂₀N₂*C₉₅H₆₄N₈O₄Zn₂