TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE

Base Information

Chemical Name:TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE
CAS No.:207405-61-6
Molecular Formula:C₁₁H₁₈N₂O₃
Molecular Weight:226.276
Hs Code.:
Mol file:207405-61-6.mol

Synonyms:TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE

Suppliers and Price of TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
5-Hydroxyimino-2-aza-bicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester 95%
1g
$ 826.00

American Custom Chemicals Corporation
TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE 95.00%
5MG
$ 498.01

Total 3 raw suppliers

Chemical Property of TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE

Chemical Property:

PSA：62.13000
LogP:1.78380

Purity/Quality:

99% ^*data from raw suppliers

5-Hydroxyimino-2-aza-bicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE

There total 4 articles about TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 198835-06-2
5-oxo-2-azabicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester

: 207405-61-6
5-oximino-2-azabicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester

Guidance literature:: With hydroxylamine hydrochloride; In pyridine; at 100 ℃; for 8h;

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 207405-61-6
5-oximino-2-azabicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: ammonium chloride

2.1: sodium tetrahydroborate; dimethyl sulfate / tetrahydrofuran / 3 h / 30 - 40 °C / Inert atmosphere

2.2: 0.67 h / 20 °C

2.3: 3 h / 60 °C

3.1: hydroxylamine hydrochloride; triethylamine / ethanol / 2 h / Reflux

With sodium tetrahydroborate; hydroxylamine hydrochloride; ammonium chloride; triethylamine; dimethyl sulfate; In tetrahydrofuran; ethanol;
DOI:10.1080/00397911003707196

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 207405-61-6
5-oximino-2-azabicyclo[2.2.1]heptane-2-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: ammonium chloride

2.1: sodium tetrahydroborate; dimethyl sulfate / tetrahydrofuran / 3 h / 30 - 40 °C / Inert atmosphere

2.2: 0.67 h / 20 °C

2.3: 3 h / 60 °C

3.1: hydroxylamine hydrochloride; triethylamine / ethanol / 2 h / Reflux

With sodium tetrahydroborate; hydroxylamine hydrochloride; ammonium chloride; triethylamine; dimethyl sulfate; In tetrahydrofuran; ethanol;
DOI:10.1080/00397911003707196