6-Ethylthio-2,2'-bipyridine

Base Information

Chemical Name:6-Ethylthio-2,2'-bipyridine
CAS No.:130897-01-7
Molecular Formula:C12H12N2S
Molecular Weight:216.307
Hs Code.:
DSSTox Substance ID:DTXSID80563981
Wikidata:Q82448543
Mol file:130897-01-7.mol

Synonyms:130897-01-7;6-ETHYLTHIO-2,2'-BIPYRIDINE;2-ethylsulfanyl-6-pyridin-2-ylpyridine;6-(Ethylthio)-2,2'-bipyridine;6-ETHYLTHIO-2,2/'-BIPYRIDINE;DTXSID80563981;6-(Ethylsulfanyl)-2,2'-bipyridine;J-400793

Suppliers and Price of 6-Ethylthio-2,2'-bipyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
6-ETHYLTHIO-2,2'-BIPYRIDINE 95.00%
5MG
$ 503.62

Total 2 raw suppliers

Chemical Property of 6-Ethylthio-2,2'-bipyridine

Chemical Property:

Boiling Point:368.8oC at 760 mmHg
Flash Point:176.8oC
PSA：51.08000
Density:1.18g/cm3
LogP:3.25560
XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:216.07211956
Heavy Atom Count:15
Complexity:187

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

6-ETHYLTHIO-2,2'-BIPYRIDINE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCSC1=CC=CC(=N1)C2=CC=CC=N2

Technology Process of 6-Ethylthio-2,2'-bipyridine

There total 10 articles about 6-Ethylthio-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 10495-73-5
2-bromo-6-(pyridin-2-yl)pyridine

: 811-51-8
sodium thioethylate

: 130897-01-7
Ethyl 6-(2,2'-pyridyl) sulfide

Guidance literature:: In 1-methyl-pyrrolidin-2-one; at 180 ℃; for 4h; under 750.075 Torr; Inert atmosphere; Autoclave;
DOI:10.1039/c8tc02882f

Reference yield: 11.0%

: 220400-08-8
6-ethylsulfinyl-6'-ethylthio-2,2'-bipyridine

: 130897-01-7
Ethyl 6-(2,2'-pyridyl) sulfide

: 220400-12-4
6,6'''-bis(ethylthio)-2,2':6',2'':6'',2'''-quaterpyridine

Guidance literature:: With methylmagnesium bromide; In tetrahydrofuran; for 0.25h; Ambient temperature;
DOI:10.3987/COM-98-S(H)57

Reference yield:

: 2402-78-0
2,6-dichloropyridine

: 130897-01-7
Ethyl 6-(2,2'-pyridyl) sulfide

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / NaH / dimethylformamide; hexamethylphosphoric acid triamide / 10 h / 0 °C

2: 73 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C

3: 70 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature

4: 54 percent / magnesium monoperoxyphthalate hexahydrate / methanol / 0.42 h / 0 °C

5: 11 percent / MeMgBr / tetrahydrofuran / 0.25 h / Ambient temperature

With methylmagnesium bromide; sodium hydride; magnesium monoperoxyphthalate hexahydrate; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.3987/COM-98-S(H)57