[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE

Base Information

Chemical Name:[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE
CAS No.:224953-43-9
Molecular Formula:C₂₈H₂₄Cl₂Zr
Molecular Weight:522.629
Hs Code.:
Mol file:224953-43-9.mol

Synonyms:[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE

Suppliers and Price of [1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)-ETHANE]ZIRCONIUM DICHLORIDE 98.00%
25G
$ 6086.85

American Custom Chemicals Corporation
[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)-ETHANE]ZIRCONIUM DICHLORIDE 98.00%
5G
$ 3280.20

American Custom Chemicals Corporation
[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)-ETHANE]ZIRCONIUM DICHLORIDE 98.00%
1G
$ 1593.90

Total 1 raw suppliers

Chemical Property of [1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE

Chemical Property:

PSA：0.00000
LogP:7.86980

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

[1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)-ETHANE]ZIRCONIUM DICHLORIDE 98.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE

There total 2 articles about [1-(9-FLUORENYL)-2-(5,6-CYCLOPENTA-2-METHYL-1-INDENYL)ETHANE]ZIRCONIUM DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.1%

: 246876-15-3
1-(fluoren-9-yl)-2-(methyl-5,6-dihydrocyclopenta[f]-1H-inden-3-yl)ethane

: 109-72-8,29786-93-4
n-butyllithium

: 10026-11-6
zirconium(IV) chloride

: 224953-43-9
[1-(9-η⁵-fluorenyl)-2-(5,6-cyclopenta-2-methyl-1-η⁵-indenyl)ethane]zirconium dichloride

Guidance literature:: In 1,4-dioxane; toluene; Ar atmosphere; cooling soln. of ligand (-78°C), mixing with soln. of n-BuLi (-78°C), warming to room temp. (2 h), cooling to -78°C, addn. of ZrCl4, warming to room temp., stirring (overnight); filtration (Celite), washing (toluene), solvent removal; elem. anal.;
DOI:10.1021/ja9833220

Reference yield: 61.0%

: dilithium (1-(fluoren-9-yl)-2-(2-methyl-5,6-dihydrocyclopenta[f]-1H-inden-1-yl)ethane)^(2-)

: 10026-11-6
zirconium(IV) chloride

: 224953-43-9
[1-(9-η⁵-fluorenyl)-2-(5,6-cyclopenta-2-methyl-1-η⁵-indenyl)ethane]zirconium dichloride

Guidance literature:: In toluene; ZrCl4 added to suspn. of Li salt at -30 °C, heated to 20 °C, stirred at 20 °C for 15 h, heated at 95 °C for 4 h, cooled to 20 °C, stand for 18 h; soln. decanted, residue extracted with toluene, concd., cooled to 0 °C, ppt. separated from mother liquor, washed with cold toluene, thenwith Et2O, dried under vac., mother liquor worked up again; elem. anal.;
DOI:10.1007/s11172-005-0264-x