Zirconium tetrachloride

Base Information

• Chemical Name: Zirconium tetrachloride
• CAS No.: 10026-11-6
• Deprecated CAS: 12331-30-5
• Molecular Formula: ZrCl4
• Molecular Weight: 233.036
• Hs Code.: 2827399000
• European Community (EC) Number: 233-058-2
• UN Number: 2503
• UNII: Z88176T871
• DSSTox Substance ID: DTXSID1044142
• Wikipedia: Zirconium tetrachloride
• Wikidata: Q205630
• Mol file: 10026-11-6.mol

Synonyms:zirconium chloride;zirconium tetrachloride;ZrCl4

Chemical Property of Zirconium tetrachloride

Chemical Property:

• Appearance/Colour: White fine powder
• Melting Point: 437 °C
• Boiling Point: 331 °C
• PSA: 0.00000
• Density: 2.8 g/cm³
• LogP: 2.75800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 231.777159
• Heavy Atom Count: 5
• Complexity: 19.1
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C:Corrosive
• Statements: R14:; R22:; R34:
• Safety Statements: S8:; S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: Cl[Zr](Cl)(Cl)Cl

Technology Process of Zirconium tetrachloride

There total 80 articles about Zirconium tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23%

→ dimethylsilyl-bis-(4,5,6,7,8,9,10,11,12,13-decahydrocyclo pentacyclododecen-2-yl)zirconiumdichloride + zirconium(IV) chloride (10026-11-6)

Guidance literature:

Reference yield:

→ zirconium(IV) chloride (10026-11-6)

Guidance literature:

Reference yield:

tetrachloro-2,2'-bipyridylzirconium (17099-99-9) → [2,2]bipyridinyl (366-18-7) + zirconium(IV) chloride (10026-11-6)

Guidance literature:

In neat (no solvent); heating under N2 above 400 °C;

upstream raw materials:

tetrachloro-2,2'-bipyridylzirconium

zirconium

chlorine

thionyl chloride

Downstream raw materials:

zirconium(IV) oxide

(2-butylcyclopenta-2,4-dienyl)zirconium(IV) chloride

zirconium tetrachloride bis(tetrahydrofuran) complex

Refernces

• 1、 Matthews, J. M.. "". . p. 815 - 839. Retrieved 1898.
• 2、 Hoenigschmid, O.. "". . . Retrieved 1906.
• 3、 Morgan, G. T.,Bowen, A. R.. "". . p. 1252 - 1261. Retrieved 1924.
• 4、 Movahedian,Raygan, Sh.,Pourabdoli. "The chlorination kinetics of zirconium dioxide mixed with carbon black". . p. 93 - 97. Retrieved 2011.
• 5、 Yajima,Segawa,Matsuzaki,Saeki. "REACTION PROCESS OF ZIRCONIUM TETRACHLORIDE WITH AMMONIA IN THE VAPOR PHASE AND PROPERTIES OF THE ZIRCONIUM NITRIDE FORMED.". . p. 2638 - 2642. Retrieved 1983.
• 6、 Bohe,Gamboa,Lopasso,Pasquevich. "Zirconium recovery from zircaloy shavings". . p. 3469 - 3474. Retrieved 1996.
• 7、 Bond, P. A.,Stephens, W. R.. "". . p. 2910 - 2922. Retrieved 1929.
• 8、 Laubengayer, A. W.,Eaton, R. B.. "". . p. 2704 - 2706. Retrieved 1940.
• 9、 -. "CATALYST FOR POLYOLEFIN PRODUCTION AND PROCESS FOR PRODUCING POLYOLEFIN". . . Retrieved 2008/06/13.