potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide

Base Information

Chemical Name:potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide
CAS No.:1242733-94-3
Molecular Formula:C₈H₇BF₃O₂*K
Molecular Weight:242.047
Hs Code.:
Mol file:1242733-94-3.mol

Synonyms:potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide

Suppliers and Price of potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide

Chemical Property:

Purity/Quality:: 99%,98%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide

There total 6 articles about potassium trifluoro[3-(methoxycarbonyl)phenyl]boranuide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1279123-63-5
potassium hydrogenfluoride

: 13675-18-8
tetrahydroxydiboron

: 2905-65-9
methyl 3-chlorobenzoate

: 1242733-94-3
potassium (meta-methoxycarbonylphenyl)trifluoroborate

Guidance literature:: With PdCl(C₆H₄C₆H₄NH₂)(Cy₂PC₆H₄-2-C₆H₂-2',4',6'-i-Pr₃); Cy₂PC₆H₄-2-C₆H₂-2',4',6'-i-Pr₃; K acetate; In ethanol; aryl chloride reacted with B2(OH)4 in EtOH in presence of catalyst (Pt-complex - ligand) and K acetate at 80°C for 2.5 h; subjected to aq. workup; treated with KHF2; purified by Soxlet extn.;
DOI:10.1021/ja303181m

Reference yield: 76.0%

: 7789-23-3
potassium fluoride

: 99769-19-4
[3-(methoxycarbonyl)phenyl]boronic acid

: 1242733-94-3
potassium (meta-methoxycarbonylphenyl)trifluoroborate

Guidance literature:: potassium fluoride; [3-(methoxycarbonyl)phenyl]boronic acid; In water; acetonitrile; at 20 ℃;

With tartaric acid; In tetrahydrofuran; water; acetonitrile; at 20 ℃; Heating;
DOI:10.1039/d1cc06341c

Reference yield: 76.0%

: 2905-65-9
methyl 3-chlorobenzoate

: 1242733-94-3
potassium (meta-methoxycarbonylphenyl)trifluoroborate

Guidance literature:: methyl 3-chlorobenzoate; With tetrahydroxydiboron; ethanol; chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[(2-(2-aminoethyl)phenyl)]palladium(II); potassium acetate; sodium t-butanolate; XPhos; at 80 ℃; for 18h; Inert atmosphere;

With potassium hydrogenfluoride; In methanol; water; at 0 - 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/ja1089759