Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Base Information

Chemical Name:Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
CAS No.:1025708-01-3
Molecular Formula:C₁₅H₂₀BBrO₄
Molecular Weight:355.036
Hs Code.:
DSSTox Substance ID:DTXSID90585992
Wikidata:Q82478016
Mol file:1025708-01-3.mol

Synonyms:1025708-01-3;ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate;ETHYL 2-BROMOBENZOATE-6-BORONIC ACID PINACOL ESTER;Benzoic acid, 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-, ethyl ester;starbld0018672;DTXSID90585992;Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoate;J-000731

Suppliers and Price of Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
ETHYL 2-BROMOBENZOATE-6-BORONIC ACID PINACOL ESTER 95.00%
5G
$ 745.50

American Custom Chemicals Corporation
ETHYL 2-BROMOBENZOATE-6-BORONIC ACID PINACOL ESTER 95.00%
5MG
$ 497.19

Total 10 raw suppliers

Chemical Property of Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Chemical Property:

Boiling Point:417.9±35.0 °C(Predicted)
PSA：44.76000
Density:1.31±0.1 g/cm3(Predicted)
LogP:2.92500
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:354.06380
Heavy Atom Count:21
Complexity:383

Purity/Quality:

98%min ^*data from raw suppliers

ETHYL 2-BROMOBENZOATE-6-BORONIC ACID PINACOL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=C(C(=CC=C2)Br)C(=O)OCC

Technology Process of Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

There total 1 articles about Ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 6091-64-1
2-bromobenzoic acid ethyl ester

: 73183-34-3
bis(pinacol)diborane

: 1025708-01-3
ethyl 2-bromo-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; diisopropyl(2-(isopropylthio)phenyl)silane; In 2-methyltetrahydrofuran; at 80 ℃; for 16h; regioselective reaction; Sealed tube; Inert atmosphere; Glovebox;
DOI:10.1039/d0ob02335c