Tris[4-(1H-imidazol-1-yl)-phenyl]amine

Base Information

• Chemical Name: Tris[4-(1H-imidazol-1-yl)-phenyl]amine
• CAS No.: 1258947-79-3
• Molecular Formula: C27H21N7
• Molecular Weight: 443.511
• Mol file: 1258947-79-3.mol

Synonyms:Tris[4-(1H-imidazol-1-yl)-phenyl]amine

Chemical Property of Tris[4-(1H-imidazol-1-yl)-phenyl]amine

Chemical Property:

• Boiling Point: 720.0±55.0 °C(Predicted)
• PKA: 6.03±0.10(Predicted)
• PSA: 56.70000
• Density: 1.25±0.1 g/cm3(Predicted)
• LogP: 5.71350
• Storage Temp.: 2-8°C

Purity/Quality:

98.5% ^*data from raw suppliers

Tris(4-(1H-imidazol-1-yl)phenyl)amine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tris[4-(1H-imidazol-1-yl)-phenyl]amine

There total 3 articles about Tris[4-(1H-imidazol-1-yl)-phenyl]amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1H-imidazole (288-32-4) + tri(p-bromophenyl)amine (4316-58-9) → tris(4-(1H-imidazol-1-yl)-phenyl)amine (1258947-79-3)

Guidance literature:

With copper(ll) sulfate pentahydrate; potassium carbonate; at 160 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201702637

Reference yield:

1H-imidazole (288-32-4) + 4-N,N-diphenylamino-1-bromobenzene (36809-26-4) → tris(4-(1H-imidazol-1-yl)-phenyl)amine (1258947-79-3)

Guidance literature:

With potassium carbonate; copper(II) oxide; sodium hydroxide; In dimethyl sulfoxide; at 170 ℃; for 30h; Time;

Reference yield:

1H-imidazole (288-32-4) + tris(4-iodophenyl)amine (4181-20-8) → tris(4-(1H-imidazol-1-yl)-phenyl)amine (1258947-79-3)

Guidance literature:

With potassium carbonate; copper(II) oxide; In dimethyl sulfoxide; at 150 ℃; for 48h;

DOI:10.1039/c0cc04724d

upstream raw materials:

1H-imidazole

tris(4-iodophenyl)amine

tri(p-bromophenyl)amine

4-N,N-diphenylamino-1-bromobenzene

Refernces

• 1、 Liu, Kang,Jiao, Shaoshao,Zhao, Huihui,Cao, Fan,Ma, Dingxuan. "Hybridization of MOFs and ionic POFs: a new strategy for the construction of bifunctional catalysts for CO2cycloaddition". . p. 1766 - 1771. Retrieved 2021.
• 2、 Wu, Hua,Liu, Hai-Yan,Liu, Bo,Yang, Jin,Liu, Ying-Ying,Ma, Jian-Fang,Liu, Yun-Yu,Bai, Hong-Ye. "Two unprecedented 3D metal-organic polyrotaxane frameworks based on a new flexible tri(imidazole) ligand". . p. 3402 - 3407. Retrieved 2011.
• 3、 Sinha, Narayan,Tan, Tristan T. Y.,Peris, Eduardo,Hahn, F. Ekkehardt. "High-Fidelity, Narcissistic Self-Sorting in the Synthesis of Organometallic Assemblies from Poly-NHC Ligands". . p. 7393 - 7397. Retrieved 2017.
• 4、 Desai, Aamod V.,Manna, Biplab,Karmakar, Avishek,Sahu, Amit,Ghosh, Sujit K.. "A Water-Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants". . p. 7811 - 7815. Retrieved 2016.
• 5、 Choudhury, Joyanta,Dutta, Tapas Kumar,Mandal, Tanmoy,Mohanty, Sunit. "Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C-H functionalization". supporting information. p. 10182 - 10185. Retrieved 2021/10/12.