Tris(4-bromophenyl)amine

Base Information

• Chemical Name: Tris(4-bromophenyl)amine
• CAS No.: 4316-58-9
• Molecular Formula: C18H12Br3N
• Molecular Weight: 482.012
• Hs Code.: 29214990
• European Community (EC) Number: 628-703-3
• NSC Number: 86666
• DSSTox Substance ID: DTXSID101347202
• Nikkaji Number: J149.788J
• Mol file: 4316-58-9.mol

Synonyms:3BrPhN SbCl6;BAHA SbCl6 cpd;TBPA amine cpd;tris(4-bromophenyl)amine;tris(4-bromophenyl)aminium hexachloroantimonate;tris(4-bromophenyl)ammoniumyl hexachloroantimonate

Chemical Property of Tris(4-bromophenyl)amine

Chemical Property:

• Appearance/Colour: pale green powder
• Vapor Pressure: 1.03E-10mmHg at 25°C
• Melting Point: 141-143 °C(lit.)
• Refractive Index: 1.692
• Boiling Point: 514.9 °C at 760 mmHg
• PKA: -4.91±0.50(Predicted)
• Flash Point: 265.2 °C
• PSA: 3.24000
• Density: 1.79 g/cm³
• LogP: 7.44390
• Storage Temp.: Refrigerator
• Solubility.: Soluble in toluene.
• XLogP3: 7.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 480.84994
• Heavy Atom Count: 22
• Complexity: 275

Purity/Quality:

99% ^*data from raw suppliers

Tris(4-bromophenyl)amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC(=CC=C1N(C2=CC=C(C=C2)Br)C3=CC=C(C=C3)Br)Br
• Uses: Tris(4-bromophenyl)amine was used in the synthesis of porous luminescent covalent--organic polymers (COPs)

Technology Process of Tris(4-bromophenyl)amine

There total 32 articles about Tris(4-bromophenyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N,N-diphenylaminobenzene (603-34-9) → tri(p-bromophenyl)amine (4316-58-9)

Guidance literature:

With N-Bromosuccinimide; triethylamine; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1002/asia.201200310

Reference yield: 93.0%

Caprinsaeure-4-methoxybenzylester (83026-08-8) → 1-decanoic acid (334-48-5) + tri(p-bromophenyl)amine (4316-58-9) + 4-methoxy-benzaldehyde (123-11-5)

Guidance literature:

With 2,6-dimethylpyridine; 2a⁽¹⁺⁾(.); In water; acetonitrile; Yield given; oxidative electrolysis;

Reference yield: 92.0%

tri(p-bromophenyl)amine (4316-58-9) → tris(p-bromophenyl)amine cation radical (4316-58-9)

Guidance literature:

With methanesulfonic acid; chloranil; In dichloromethane; at 25 ℃; for 0.333333h;

DOI:10.3891/acta.chem.scand.52-0114

upstream raw materials:

N,N-diphenylaminobenzene

2,3-diazabicyclo[2.2.2]oct-2-ene

tris(4-bromophenyl)ammoniumyl hexafluoroantimonate

2-diazo-acetophenone

Downstream raw materials:

methyl radical

carbon dioxide

4-cyano-4′,4′′-dibromotriphenylamine

(2-cyano-4-bromophenyl)-bis(4-bromophenyl)amine

Refernces

• 1、 Zhao, Li,Liu, Cheng-Fang,Xu, Wei-Dong,Jiang, Yi,Lai, Wen-Yong,Huang, Wei. "Donor-acceptor star-shaped conjugated macroelectrolytes: Synthesis, light-harvesting properties, and self-assembly-induced f?rster resonance energy transfer". . p. 6730 - 6739. Retrieved 2015.
• 2、 Doan, Bao Kim,Luu, Tam Hoang,Nguyen, Ha Tran,Nguyen, Le-Thu T.,Nguyen, Tam Huu,Nguyen, Vuong Mau,Tran, Tung Viet Tuan,Van, Toai Pham. "One-pot synthesis of star-shaped conjugated oligomers based on 3-hexylthiophene, pyrene and triphenylamine as TNT chemosensors". . . Retrieved 2020.
• 3、 Bonesi, Sergio M.,Protti, Stefano,Albini, Angelo. "Photochemical Co-Oxidation of Sulfides and Phosphines with Tris(p-bromophenyl)amine. A Mechanistic Study". . p. 8104 - 8113. Retrieved 2018.
• 4、 Méndez, Maria,Nazeeruddin, Mohammad Khaja,Palomares, Emilio Jose,Pudi, Ravi,Rodríguez-Seco, Cristina,Roldán-Carmona, Cristina. "Minimization of Carrier Losses for Efficient Perovskite Solar Cells through Structural Modification of Triphenylamine Derivatives". . p. 5303 - 5307. Retrieved 2020.
• 5、 Zhang, Hongyu,Huo, Cheng,Zhang, Jingying,Zhang, Peng,Tian, Wenjing,Wang, Yue. "Efficient single-layer electroluminescent device based on a bipolar emitting boron-containing material". . p. 281 - 283. Retrieved 2006.
• 6、 Mohamed, Mohamed Gamal,Elsayed, Mohamed Hammad,Elewa, Ahmed M.,EL-Mahdy, Ahmed F. M.,Yang, Cheng-Han,Mohammed, Ahmed A. K.,Chou, Ho-Hsiu,Kuo, Shiao-Wei. "Pyrene-containing conjugated organic microporous polymers for photocatalytic hydrogen evolution from water". . p. 2229 - 2241. Retrieved 2021/04/09.
• 7、 Huang, Bolong,Li, Jiahua,Sun, Jibin,Sun, Mingzi,Tang, Tianhong,Wang, Zhengping,Wong, Wai-Yeung,Xie, Zheng,Xu, Linli,Zhang, Hongyang,Zhang, Jianqi. "Metallated Graphynes as a New Class of Photofunctional 2D Organometallic Nanosheets". supporting information. p. 11326 - 11334. Retrieved 2021/04/09.