2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate

Base Information

Chemical Name:2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate
CAS No.:16643-37-1
Molecular Formula:C₂₃H₂₈O₁₂
Molecular Weight:496.468
Hs Code.:
Mol file:16643-37-1.mol

Synonyms:2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate;Salicin pentaacetate

Suppliers and Price of 2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of 2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate

Chemical Property:

Melting Point:139-140 °C
Boiling Point:546.8±50.0 °C(Predicted)
Density:1.31±0.1 g/cm3(Predicted)

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Hazard Codes:

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Technology Process of 2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate

There total 3 articles about 2-[(Acetyloxy)methyl]phenyl β-D-glucopyranoside 2,3,4,6-tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 108-24-7
acetic anhydride

: 138-52-3
D-(-)-salicin

: 16643-37-1
salicin pentaacetate

Guidance literature:: With potassium carbonate; In 1,4-dioxane; at 60 ℃; for 16h;

Reference yield:

: 4336-91-8
3-bromo-2-pyridyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

: 2848-25-1
2-acetoxyphenol

: 16643-37-1
salicin pentaacetate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; for 1h; diastereoselective reaction;
DOI:10.1055/s-0035-1561461

Reference yield:

: 604-69-3
β-D-glucose pentaacetate

: 16643-37-1
salicin pentaacetate

Guidance literature:: Multi-step reaction with 3 steps

1: acetic acid; hydrogen bromide; acetic anhydride / 2 h / 20 °C / Inert atmosphere

2: toluene / 3 h / Inert atmosphere; Reflux

3: boron trifluoride diethyl etherate / dichloromethane / 1 h

With boron trifluoride diethyl etherate; hydrogen bromide; acetic anhydride; acetic acid; In dichloromethane; toluene;
DOI:10.1055/s-0035-1561461