Chlorohydridotris(triphenylphosphine) rutheniuM(II) toluene adduct

Base Information

• Chemical Name: Chlorohydridotris(triphenylphosphine) rutheniuM(II) toluene adduct
• CAS No.: 217661-36-4
• Molecular Formula: C61H53ClP3Ru
• Molecular Weight: 1015.517803
• Mol file: 217661-36-4.mol

Synonyms:bistriphenylphosphine palladium diacetate;

Chemical Property of Chlorohydridotris(triphenylphosphine) rutheniuM(II) toluene adduct

Chemical Property:

• Flash Point: >113℃
• PSA: 40.77000
• LogP: 9.33340
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorohydridotris(triphenylphosphine) ruthenium(II) toluene adduct ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Reactant for synthesis of:Dithiolate-bridged ruthenium-rhodium heterobimetallic dihydride complex Amido / phosphine pincer hydrides of ruthenium

Technology Process of Chlorohydridotris(triphenylphosphine) rutheniuM(II) toluene adduct

There total 1 articles about Chlorohydridotris(triphenylphosphine) rutheniuM(II) toluene adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + toluene (108-88-3,15644-74-3,16713-13-6) → (PPh3)3RuHCl*PhMe (217661-36-4)

Guidance literature:

With H₂; triethylamine; In toluene; Hallman, P.S.; McGarvey, B. R.; Wilkinson, G. J. Chem. Soc. A 1968, 3143-3150;

DOI:10.1021/ja00415a021

Reference yield: 93.0%

(PPh3)3RuHCl*PhMe (217661-36-4) + tris-(m-sulfonatophenyl)phosphine (91171-35-6) → [Ru(H)(Cl)(tris(m-sulfonatophenyl)phosphine)3]

Guidance literature:

In tetrahydrofuran; water; (Ar); Ru-compd. soln. in THF mixing with org. compd. soln. in H2O;

DOI:10.1016/S1381-1169(96)00232-4

Reference yield: 92.0%

(PPh3)3RuHCl*PhMe (217661-36-4) + ((C6H11)2PCH2Si(CH3)2)2N(1-)*Li(1+)*0.75(C2H5)2O=((C6H11)2PCH2Si(CH3)2)2NLi*0.75(C2H5)2O → [(cyclohexyl)2PCH2SiMe2]2NRu(II)H(PPh3) (568593-28-2)

Guidance literature:

In toluene; under inert atm., Schlenk flask; stirred at room temp. for 48; filtered, volatiles removed to liquid N2 trap, solid powdered in mortar,free PPh3 removed by sublimation (60°C, 0.003 torr, 1 week);

DOI:10.1039/b206202j

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

toluene

Downstream raw materials:

hyper-closo-2-(C₆H₅)-6,6-[P(C₆H₅)3]2-6,2,3-RuC₂B₇H₈

[closo-1,1,3-(PPH₃)3-1-H-1,2,4-RuC₂B₈H₉]

hyper-closo-6,6-[P(C₆H₅)3]2-6,2,3-RuC₂B₇H₉

hyper-closo-2,3-(CH₃)2-6,6-[P(C₆H₅)3]2-6,2,3-RuC₂B₇H₉