3-(3-Fluoro-4-methylphenyl)-1-propene

Base Information

Chemical Name:3-(3-Fluoro-4-methylphenyl)-1-propene
CAS No.:842124-26-9
Molecular Formula:C10H11F
Molecular Weight:150.19
Hs Code.:2903999090
DSSTox Substance ID:DTXSID20374614
Wikidata:Q82163221
Mol file:842124-26-9.mol

Synonyms:3-(3-Fluoro-4-methylphenyl)-1-propene;842124-26-9;2-fluoro-1-methyl-4-prop-2-enylbenzene;4-allyl-2-fluoro-1-methylbenzene;DTXSID20374614;MFCD06201192;AKOS006345472;CS-0267247;EN300-698386;2-fluoro-1-methyl-4-(prop-2-en-1-yl)benzene

Suppliers and Price of 3-(3-Fluoro-4-methylphenyl)-1-propene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
5g
$ 930.00

Rieke Metals
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
2g
$ 391.00

Rieke Metals
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
1g
$ 256.00

Matrix Scientific
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
1g
$ 252.00

Matrix Scientific
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
2g
$ 364.00

Matrix Scientific
3-(3-Fluoro-4-methylphenyl)-1-propene 97%
5g
$ 812.00

Crysdot
3-(3-Fluoro-4-methylphenyl)-1-propene 95+%
5g
$ 804.00

American Custom Chemicals Corporation
3-(3-FLUORO-4-METHYLPHENYL)-1-PROPENE 95.00%
1G
$ 354.90

Total 6 raw suppliers

Chemical Property of 3-(3-Fluoro-4-methylphenyl)-1-propene

Chemical Property:

Vapor Pressure:1.19mmHg at 25°C
Boiling Point:181°C at 760 mmHg
Flash Point:54.9°C
PSA：0.00000
Density:0.973g/cm³
LogP:2.86260
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:150.084478513
Heavy Atom Count:11
Complexity:131

Purity/Quality:

98%Min ^*data from raw suppliers

3-(3-Fluoro-4-methylphenyl)-1-propene 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C=C(C=C1)CC=C)F

Technology Process of 3-(3-Fluoro-4-methylphenyl)-1-propene

There total 2 articles about 3-(3-Fluoro-4-methylphenyl)-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 2551-83-9
allyltrimethoxysilane

: 345-35-7
2-fluorobenzyl chloride

: 842124-26-9
4-allyl-2-fluoro-1-methylbenzene

Guidance literature:: allyltrimethoxysilane; 2-fluorobenzyl chloride; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; at 20 ℃; for 18h; Inert atmosphere;

With toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; at 20 ℃; for 0.166667h; regioselective reaction; Inert atmosphere;
DOI:10.1021/acs.joc.7b00678

Reference yield:

: 106-95-6
allyl bromide

: 185077-02-5
(3-fluoro-4-methylphenyl)magnesium bromide

: 842124-26-9
4-allyl-2-fluoro-1-methylbenzene

Guidance literature:: DOI:10.1016/j.bmcl.2004.01.102

Reference yield:

: 842124-26-9
4-allyl-2-fluoro-1-methylbenzene

: Carbamic acid (6Z,11Z)-(1S,2S,3R,4S,8S,9S,10S)-14-(3-fluoro-4-methyl-phenyl)-3,9-dihydroxy-2,4,6,8,10-pentamethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-tetradeca-6,11-dienyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 9-BBN

1.2: aq. H₂O₂; NaOH

2.1: I₂; PPh₃; imidazole

3.1: toluene / 80 °C

4.1: n-BuLi

5.1: K₂CO₃; MeOH

6.1: HCl / methanol

With 1H-imidazole; hydrogenchloride; methanol; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; iodine; potassium carbonate; triphenylphosphine; In methanol; toluene; 4.1: Wittig reaction;
DOI:10.1016/j.bmcl.2004.01.102