ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME

Base Information

• Chemical Name: ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME
• CAS No.: 101023-70-5
• Molecular Formula: C9H8ClNO3
• Molecular Weight: 213.62
• Hs Code.: 2928000090
• Mol file: 101023-70-5.mol

Synonyms:ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME

Chemical Property of ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME

Chemical Property:

• PSA: 58.89000
• LogP: 1.84780

Purity/Quality:

99% ^*data from raw suppliers

Methyl 4-(chloro(hydroxyimino)methyl)benzoate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME

There total 7 articles about ALPHA-CHLORO-4-METHOXYCARBONYLBENZALDOXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-(hydroxyiminomethyl)benzoic acid methyl ester (53148-13-3) → 4-methoxycarbonylbenzhydroxamic acid chloride (101023-70-5)

Guidance literature:

With N-chloro-succinimide; In chloroform; at 20 ℃; for 4h;

Reference yield: 90.0%

C13H16ClNO3 (1431323-57-7) → 4-methoxycarbonylbenzhydroxamic acid chloride (101023-70-5)

Guidance literature:

With trifluoroacetic acid;

DOI:10.1016/j.bmcl.2013.03.115

Reference yield:

methyl 4-formylbenzoate (1571-08-0) → 4-methoxycarbonylbenzhydroxamic acid chloride (101023-70-5)

Guidance literature:

Multi-step reaction with 2 steps

1: hydroxylamine hydrochloride; sodium hydroxide / tetrahydrofuran; water / 0.17 h / 0 °C

2: N-chloro-succinimide / N,N-dimethyl-formamide / 6 h / 20 °C

With N-chloro-succinimide; hydroxylamine hydrochloride; sodium hydroxide; In tetrahydrofuran; water; N,N-dimethyl-formamide;

DOI:10.1055/s-0036-1588655

upstream raw materials:

4-(hydroxyiminomethyl)benzoic acid methyl ester

methyl 4-formylbenzoate

Monomethyl terephthalate

C₁₃H₁₆ClNO₃

Downstream raw materials:

C₂₄H₂₄N₂O₅

methyl 4-[5-(4-n-pentyloxyphenyl)isoxazol-3-yl]benzoate

4-{5-[4-(pentyloxy)phenyl]-1,2-oxazol-3-yl}benzoic acid

1-[[4-[5-(4-pentyloxyphenyl)isoxazol-3-yl]benzoyl]oxy]-1H-1,2,3-benzotriazole