Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)-

Base Information

Chemical Name:Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)-
CAS No.:14586-49-3
Molecular Formula:C10H5 N O5 W
Molecular Weight:403.003
Hs Code.:

Synonyms:(Pyridine)tungstenpentacarbonyl (6CI); Tungsten, pentacarbonyl(pyridine)- (7CI,8CI); NSC 168781;Pentacarbonyl(pyridine)tungsten; Pyridinepentacarbonyltungsten

Suppliers and Price of Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)-

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)-

There total 10 articles about Tungsten,pentacarbonyl(pyridine)-, (OC-6-22)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.5%

: 1,4-bis(2-ethoxy-1,1,1,1,1-pentacarbonyl-1-tungsta-1-ethen-2-yl)-2a-methyl-2,5-diphenyl-2a,3,6,7-tetrahydro-8-oxa-5a-azacyclobuta[d]indene

: 14586-49-3
(pyridine)pentacarbonyltungsten⁽⁰⁾

: 4-(2-ethoxy-1,1,1,1,1-pentacarbonyl-1-tungsta-1-ethen-2-yl)-2a-methyl-2,5-diphenyl-2a,3,6,7-tetrahydro-8-oxa-5a-azacyclobuta[d]indene-1-carboxylic acid ethyl ester

Guidance literature:: With pyridine N-oxide; In dichloromethane; N2 atm.; complex was reacted with pyridine N-oxide in dry CH2Cl2 with stirring at ambient temp.; volatiles were removed under reduced pressure, chromy. on silica gel, hexane-CH2Cl2 1:1, volatiles were removed under reduced pressure, recrystd. from pentane at -20°C; elem. anal.;
DOI:10.1021/om049213d

Reference yield: 74.0%

: 108417-88-5
pentacarbonyl(2-ethoxy-2-phenyl-4-pentenenitrile-N)tungsten⁽⁰⁾

: 14586-49-3
(pyridine)pentacarbonyltungsten⁽⁰⁾

: 108451-17-8
2-ethoxy-2-phenyl-4-pentenenitrile

Guidance literature:: With pyridine; In Petroleum ether; addn. of pyridine to W-compound, warming to 40°C for 40 min under inert gas; crystn. of W-complex at 0°C, decantation and chromy. on silica gel (petroleum ether) gives pentenenitrile and residue of W-compound, elem. anal. of pentenenitrile;