2-(But-3-en-1-yl)-1,1'-biphenyl

Base Information

• Chemical Name: 2-(But-3-en-1-yl)-1,1'-biphenyl
• CAS No.: 157581-09-4
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• DSSTox Substance ID: DTXSID00602942
• Nikkaji Number: J3.166.497G
• Wikidata: Q82500153
• Mol file: 157581-09-4.mol

Synonyms:4-(2-Biphenyl)-1-butene;157581-09-4;2-(But-3-en-1-yl)-1,1'-biphenyl;1-but-3-enyl-2-phenylbenzene;MFCD09801139;2-But-3-enylbiphenyl;DTXSID00602942;AKOS016016878

Chemical Property of 2-(But-3-en-1-yl)-1,1'-biphenyl

Chemical Property:

• Vapor Pressure: 0.000397mmHg at 25°C
• Boiling Point: 327°C at 760 mmHg
• Flash Point: 158.9°C
• PSA: 0.00000
• Density: 0.965g/cm³
• LogP: 4.47220
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 208.125200510
• Heavy Atom Count: 16
• Complexity: 200

Purity/Quality:

97% ^*data from raw suppliers

4-(2-Biphenyl)-1-butene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCCC1=CC=CC=C1C2=CC=CC=C2

Technology Process of 2-(But-3-en-1-yl)-1,1'-biphenyl

There total 8 articles about 2-(But-3-en-1-yl)-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-(fluoromethyl)-1,1’-biphenyl + allyl-trimethyl-silane (762-72-1) → 2-(but-3-en-1-yl)-1,1′-biphenyl (157581-09-4)

Guidance literature:

With C₂₄H₂₉N₂P⁽²⁺⁾*2C₂₄BF₂₀^(1-); In dichloromethane; at 25 ℃; for 4h; Reagent/catalyst; Inert atmosphere;

DOI:10.1021/acs.organomet.8b00686

Reference yield: 92.0%

1-iodo-2-(prop-2-en-1-yl)benzene (74190-01-5) + phenylzinc iodide (23665-09-0) → 2-(but-3-en-1-yl)-1,1′-biphenyl (157581-09-4)

Guidance literature:

With lithium chloride; In tetrahydrofuran; toluene; at 110 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201308200

Reference yield: 92.0%

triphenylboroxine (3262-89-3) + 1-(but-3-en-1-yl)-2-iodobenzene (24892-64-6) → 2-(but-3-en-1-yl)-1,1′-biphenyl (157581-09-4)

Guidance literature:

triphenylboroxine; With potassium tert-butylate; zinc(II) chloride; In 1-methyl-pyrrolidin-2-one; at 23 ℃; for 1h; Inert atmosphere; Glovebox;

1-(but-3-en-1-yl)-2-iodobenzene; In 1-methyl-pyrrolidin-2-one; at 110 ℃; for 24h; Inert atmosphere; Glovebox;

DOI:10.1002/anie.201802813

upstream raw materials:

1-(but-3-en-1-yl)-2-iodobenzene

1-iodo-2-(prop-2-en-1-yl)benzene

phenylzinc iodide

iodobenzene

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