1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE

Base Information

Chemical Name:1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE
CAS No.:4105-61-7
Molecular Formula:C16H18O5
Molecular Weight:290.316
Hs Code.:
Mol file:4105-61-7.mol

Synonyms:1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE

Suppliers and Price of 1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE 95.00%
5MG
$ 501.69

Total 3 raw suppliers

Chemical Property of 1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE

Chemical Property:

Vapor Pressure:5.84E-06mmHg at 25°C
Boiling Point:379.5°C at 760 mmHg
Flash Point:166°C
PSA：53.99000
Density:1.217g/cm³
LogP:2.27060

Purity/Quality:: 1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE

There total 5 articles about 1,2-O-ISOPROPYLIDENE-3-BENZOYLOXY-5,6-DIDEOXY-GLUCOFURANOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 37614-73-6
1,2-O-isopropylidene-α-D-glucofuranose 3-O-benzoate

: 4105-61-7
3-O-Benzyl-5,6-didehydro-5,6-dideoxy-1,2-isopropyliden-α-D-xylo-hexofuranose

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In toluene; for 5h; Heating;
DOI:10.1016/j.carres.2004.12.024

Reference yield: 38.3%

: 182412-45-9
Benzoic acid (3aR,5R,6S,6aR)-2,2-dimethyl-5-((R)-2-thioxo-[1,3]dioxolan-4-yl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 4105-61-7
3-O-Benzyl-5,6-didehydro-5,6-dideoxy-1,2-isopropyliden-α-D-xylo-hexofuranose

: 182412-49-3
Benzoic acid (3aR,5S,6S,6aR)-2,2-dimethyl-5-((S)-2-oxo-[1,3]oxathiolan-5-yl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 182412-42-6
Benzoic acid (3aR,5S,6R,6aR)-2,2-dimethyl-5-((S)-2-oxo-[1,3]oxathiolan-4-yl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 182412-41-5
3-O-benzoyl-5,6-O-carbonyl-1,2-isopropylidene-5-thio-α-D-glucofuranose

Guidance literature:: With bis(tri-n-butyltin); In benzene; at 10 - 15 ℃; for 4h; Further byproducts given; Irradiation;

Reference yield:

: 2816-87-7
1,2-di-O-isopropylidene-5,6-O-thiocarbonyl-α-D-glucofuranose

: 4105-61-7
3-O-Benzyl-5,6-didehydro-5,6-dideoxy-1,2-isopropyliden-α-D-xylo-hexofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / pyridine

2: 6.1 percent / (Bu₃Sn)2 / benzene / 4 h / 10 - 15 °C / Irradiation

With pyridine; bis(tri-n-butyltin); In benzene;