methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Base Information

Chemical Name:methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate
CAS No.:1109277-67-9
Molecular Formula:C₁₀H₁₃F₃O₅S
Molecular Weight:302.271
Hs Code.:
Mol file:1109277-67-9.mol

Synonyms:methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Suppliers and Price of methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Chemical Property:

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

There total 4 articles about methyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 66405-41-2
(4-oxo-cyclohexyl)-acetic acid methyl ester

: 1109277-67-9
methyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: for 2h;

Reference yield:

: 14199-15-6
Methyl 4-hydroxyphenylacetate

: 1109277-67-9
methyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogen; Rh/Al₂O₃

2: 2,6-di-tert-butyl-4-methylpyridine / dichloromethane / 20.5 h / 0 - 20 °C / Inert atmosphere

With 2,6-di-tert-butyl-4-methylpyridine; Rh/Al₂O₃; hydrogen; In dichloromethane;

Reference yield:

: 172270-85-8
8-(methoxyformylmethylene)-1,4-dioxaspiro[4.5]decane

: 1109277-67-9
methyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogen; palladium 10% on activated carbon / ethyl acetate / 8 h / 20 °C

1.2: 4 h / 20 °C

2.1: 2,6-di-tert-butyl-pyridine / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

2.2: 9 h / 20 °C / Inert atmosphere

With 2,6-di-tert-butyl-pyridine; palladium 10% on activated carbon; hydrogen; In dichloromethane; ethyl acetate;
DOI:10.1002/anie.201706018