3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose

Base Information

Chemical Name:3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose
CAS No.:13322-89-9
Molecular Formula:C₁₉H₂₆O₆
Molecular Weight:350.40614
Hs Code.:
DSSTox Substance ID:DTXSID301194687
Nikkaji Number:J81.598E
Mol file:13322-89-9.mol

Synonyms:13322-89-9;SCHEMBL5343152;CSVOEMJSHCCUHW-UYTYNIKBSA-N;DTXSID301194687;3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose;1,2-O-Cyclohexylidene-3-O-(phenylmethyl)-alpha-D-glucofuranose

Suppliers and Price of 3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:5
Exact Mass:350.17293854
Heavy Atom Count:25
Complexity:432

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CCC2(CC1)OC3C(C(OC3O2)C(CO)O)OCC4=CC=CC=C4
Isomeric SMILES:C1CCC2(CC1)O[C@@H]3[C@H]([C@H](O[C@@H]3O2)[C@@H](CO)O)OCC4=CC=CC=C4

Technology Process of 3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose

There total 4 articles about 3-O-Benzyl-1-O,2-O-cyclohexylidene-alpha-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 3-O-benzyl-1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose

: 13322-89-9
3-O-Benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose

Guidance literature:: With sodium dodecyl-sulfate; benzyl bromide; In water; at 20 ℃; for 16h; chemoselective reaction;
DOI:10.1021/acs.joc.9b02561

Reference yield:

: 23397-76-4
1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose

: 13322-89-9
3-O-Benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: NaOH; n-Bu₄NBr / CH₂Cl₂; H₂O / 16 h / 20 °C

2: AcOH / H₂O / 18 h / 20 °C

With sodium hydroxide; tetrabutylammomium bromide; acetic acid; In dichloromethane; water;
DOI:10.1016/j.tetlet.2004.06.017

Reference yield:

: 100-39-0
benzyl bromide

: 13322-89-9
3-O-Benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: NaOH; n-Bu₄NBr / CH₂Cl₂; H₂O / 16 h / 20 °C

2: AcOH / H₂O / 18 h / 20 °C

With sodium hydroxide; tetrabutylammomium bromide; acetic acid; In dichloromethane; water;
DOI:10.1016/j.tetlet.2004.06.017