tBuXPhos Pd G3

Base Information

• Chemical Name: tBuXPhos Pd G3
• CAS No.: 1447963-75-8
• Molecular Formula: CH₃O₃S*C₄₁H₅₅NPPd
• Molecular Weight: 794.387
• Hs Code.: 2843909000
• Mol file: 1447963-75-8.mol

Synonyms:Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [t-BuXPhos Palladacycle];tBuXPhos Pd G3;Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);[(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate;tBuXPhos Pd G3 97%;[2'-(Amino)[1,1'-biphenyl]-2-yl][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium

Chemical Property of tBuXPhos Pd G3

Chemical Property:

• Melting Point: 130-140°C
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

98%,Pd>13.0 ^*data from raw suppliers

tBuXPhos Pd G3 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Physical properties: tBuXPhos-Pd-G3 is in the form of a dark grey crystalline powder.
• Uses: tBuXPhos Pd G3 may be used to synthesize 4-cyano-7-azaindole from 4-chloro-7-azaindole by cyanation reaction. It may also be used for the α-arylation reaction of acetate esters at room temperature.

Technology Process of tBuXPhos Pd G3

There total 1 articles about tBuXPhos Pd G3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer (1435520-65-2) + tert-butyl XPhos (564483-19-8) → C41H55NPPd(1+)*CH3O3S(1-) (1445085-66-4,1447963-75-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

DOI:10.1039/c2sc20903a

upstream raw materials:

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

tert-butyl XPhos

Refernces