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(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer, also known as Pd(dsbp)2, is a palladium complex that consists of two palladium atoms bridged by a (2'-amino-1,1'-biphenyl-2-yl)methanesulfonato ligand. This dimeric compound is characterized by its high catalytic activity and selectivity, making it a valuable tool in the field of organometallic chemistry and catalysis. The presence of the biphenyl-2-yl moiety in the ligand provides rigidity to the complex, enhancing its stability and reactivity.

1435520-65-2

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1435520-65-2 Usage

Uses

Used in Organic Synthesis:
Pd(dsbp)2 is used as a catalyst for various organic synthesis reactions, including cross-coupling reactions and C-H activation. Its high catalytic activity and selectivity make it a valuable tool in the field of organometallic chemistry and catalysis.
Used in Pharmaceutical Industry:
Pd(dsbp)2 is used as a catalyst in the synthesis of pharmaceutical compounds, enabling the efficient production of complex molecules with high selectivity and yield.
Used in Chemical Research:
Pd(dsbp)2 is employed as a catalyst in academic and industrial research settings, facilitating the development of new synthetic methods and the discovery of novel chemical compounds.
Used in Material Science:
Pd(dsbp)2 is utilized as a catalyst in the synthesis of advanced materials, such as polymers, nanoparticles, and other functional materials, contributing to the development of new technologies and applications in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 1435520-65-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,3,5,5,2 and 0 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1435520-65:
(9*1)+(8*4)+(7*3)+(6*5)+(5*5)+(4*2)+(3*0)+(2*6)+(1*5)=142
142 % 10 = 2
So 1435520-65-2 is a valid CAS Registry Number.

1435520-65-2Relevant academic research and scientific papers

Can Palladium Acetate Lose Its "saltiness"? Catalytic Activities of the Impurities in Palladium Acetate

Carole, William A.,Bradley, Jonathan,Sarwar, Misbah,Colacot, Thomas J.

supporting information, p. 5472 - 5475 (2015/11/18)

Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state 13C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.

Design and preparation of new palladium precatalysts for C-C and C-N cross-coupling reactions

Bruno, Nicholas C.,Tudge, Matthew T.,Buchwald, Stephen L.

, p. 916 - 920 (2013/06/05)

A series of easily prepared, phosphine-ligated palladium precatalysts based on the 2-aminobiphenyl scaffold have been prepared. The role of the precatalyst-associated labile halide (or pseudohalide) in the formation and stability of the palladacycle has been examined. It was found that replacing the chloride in the previous version of the precatalyst with a mesylate leads to a new class of precatalysts with improved solution stability and that are readily prepared from a wider range of phosphine ligands. The differences between the previous version of precatalyst and that reported here are explored. In addition, the reactivity of the latter is examined in a range of C-C and C-N bond forming reactions.

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