1435520-65-2 Usage
General Description
The chemical (2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer, also known as Pd(dsbp)2, is a palladium complex that consists of two palladium atoms bridged by a (2'-amino-1,1'-biphenyl-2-yl)methanesulfonato ligand. This dimeric compound is commonly used as a catalyst in various organic synthesis reactions, including cross-coupling reactions and C-H activation. The presence of the biphenyl-2-yl moiety in the ligand provides rigidity to the complex, enhancing its stability and reactivity. Pd(dsbp)2 is known for its high catalytic activity and selectivity, making it a valuable tool in the field of organometallic chemistry and catalysis.
Check Digit Verification of cas no
The CAS Registry Mumber 1435520-65-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,3,5,5,2 and 0 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1435520-65:
(9*1)+(8*4)+(7*3)+(6*5)+(5*5)+(4*2)+(3*0)+(2*6)+(1*5)=142
142 % 10 = 2
So 1435520-65-2 is a valid CAS Registry Number.
1435520-65-2Relevant articles and documents
Can Palladium Acetate Lose Its "saltiness"? Catalytic Activities of the Impurities in Palladium Acetate
Carole, William A.,Bradley, Jonathan,Sarwar, Misbah,Colacot, Thomas J.
supporting information, p. 5472 - 5475 (2015/11/18)
Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state 13C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.
