3,4-DIIODOBENZOIC ACID METHYL ESTER

Base Information

• Chemical Name: 3,4-DIIODOBENZOIC ACID METHYL ESTER
• CAS No.: 916975-33-2
• Molecular Formula: C8H6I2O2
• Molecular Weight: 387.943
• Mol file: 916975-33-2.mol

Synonyms:3,4-DIIODOBENZOIC ACID METHYL ESTER

Chemical Property of 3,4-DIIODOBENZOIC ACID METHYL ESTER

Chemical Property:

• PSA: 26.30000
• LogP: 2.68240

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,4-DIIODOBENZOIC ACID METHYL ESTER

There total 1 articles about 3,4-DIIODOBENZOIC ACID METHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

4-amino-3-iodobenzoic acid methyl ester (19718-49-1) → 3,4-diiodobenzoic acid methyl ester (916975-33-2)

Guidance literature:

4-amino-3-iodobenzoic acid methyl ester; With hydrogenchloride; sodium nitrite; for 0.5h;

With potassium iodide; In water; at 20 ℃; Further stages.;

DOI:10.1002/adsc.200600469

Reference yield: 95.0%

3,4-diiodobenzoic acid methyl ester (916975-33-2) + 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (72824-04-5) → methyl 3,4-diallylbenzoate

Guidance literature:

With cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 48h; Heating;

DOI:10.1002/adsc.200600469

Reference yield: 67.0%

2-ethynylpyridine (1945-84-2) + 3,4-diiodobenzoic acid methyl ester (916975-33-2) → C22H14N2O2

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 50 ℃; for 20h;

upstream raw materials:

4-amino-3-iodobenzoic acid methyl ester

Downstream raw materials:

methyl 3,4-bis-perfluoroethylbenzoate

Refernces