1-Methoxymethylcyclooctatetraene

Base Information

• Chemical Name: 1-Methoxymethylcyclooctatetraene
• CAS No.: 30844-13-4
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.205
• Mol file: 30844-13-4.mol

Synonyms:1-Methoxymethylcyclooctatetraene

Chemical Property of 1-Methoxymethylcyclooctatetraene

Chemical Property:

• Boiling Point: 226.3±19.0 °C(Predicted)
• PSA: 9.23000
• Density: 0.943±0.06 g/cm3(Predicted)
• LogP: 2.24140

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Methoxymethylcyclooctatetraene

There total 3 articles about 1-Methoxymethylcyclooctatetraene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

[(1E,3Z,5Z,7Z)-cycloocta-1,3,5,7-tetraen-1-yl]methanol (56900-54-0) + methyl iodide (74-88-4) → (methoxymethyl)cyclooctatetraene (30844-13-4)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; for 2h;

DOI:10.1021/ja00366a005

Reference yield:

C11H12O2 → (methoxymethyl)cyclooctatetraene (30844-13-4) + 4b-Methoxymethyl-2a,2b,4a,4b-tetrahydro-cyclopropa[cd]pentalene + 4a-Methoxymethyl-2a,2b,4a,4b-tetrahydro-cyclopropa[cd]pentalene

Guidance literature:

In methanol; for 0.833333h; Yield given. Yields of byproduct given; Irradiation;

DOI:10.1016/S0040-4039(98)00890-9

Reference yield:

→ (methoxymethyl)cyclooctatetraene (30844-13-4)

Guidance literature:

DOI:10.1021/ja00831a013

upstream raw materials:

[(1E,3Z,5Z,7Z)-cycloocta-1,3,5,7-tetraen-1-yl]methanol

methyl iodide