Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)-

Base Information

Chemical Name:Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)-
CAS No.:20437-10-9
Molecular Formula:C28H18N2NiO2
Molecular Weight:473.153
Hs Code.:
European Community (EC) Number:243-820-6
DSSTox Substance ID:DTXSID1066609

Synonyms:20437-10-9;Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-.kappa.N)methylidyne]]bis[2-naphthalenolato-.kappa.O]](2-)]-, (SP-4-2)-;EINECS 243-820-6;DTXSID1066609;Nickel, ((1,1'-(1,2-phenylenebis((nitrilo-kappaN)methylidyne))bis(2-naphthalenolato-kappaO))(2-))-, (SP-4-2)-;((1,1'-(1,2-Phenylenebis(nitrilomethylidyne))bis(2-naphtholato))(2-)-N,N',O,O')nickel;Nickel, ((1,1'-(1,2-phenylenebis(nitrilomethylidyne))bis(2-naphthalenolato))(2-)-N,N',O,O')-, (SP-4-2)-

Suppliers and Price of Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 6 raw suppliers

Chemical Property of Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)-

Chemical Property:

Boiling Point:708.9°Cat760mmHg
Flash Point:493.3°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:472.072169
Heavy Atom Count:33
Complexity:608

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C=CC(=C2C=NC3=CC=CC=C3N=CC4=C(C=CC5=CC=CC=C54)[O-])[O-].[Ni+2]

Technology Process of Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)-

There total 4 articles about Nickel, [[1,1'-[1,2-phenylenebis[(nitrilo-kappaN)methylidyne]]bis[2-naphthalenolato-kappaO]](2-)]-, (SP-4-2)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.3%

: 33215-85-9
N,N-bis(1-naphthaldimine)-o-phenylenediamine

: 6018-89-9
nickel(II) acetate tetrahydrate

: 20437-10-9
(1,1'-[o-phenylenebis(nitrilomethylidyne)]di-2-naphtholato-κ4O,N,N',O')nickel(II)

Guidance literature:: In methanol; water; byproducts: CH3COOH; aq. soln. of Ni salt added to hot MeOH soln. of ligand (molar ratio 1:1); refluxed for 2 h; filtered from ice-cooled react. mixt.; washed with MeOH and Et2O; driedat 50°C overnight; elem. anal.;
DOI:10.1080/00945710009351870

Reference yield: 70.0%

: 33215-85-9
N,N-bis(1-naphthaldimine)-o-phenylenediamine

: 14701-22-5
nickel(II)

: 20437-10-9
(1,1'-[o-phenylenebis(nitrilomethylidyne)]di-2-naphtholato-κ4O,N,N',O')nickel(II)

Guidance literature:: In ethanol; water; refluxing mixture of ethanolic soln. of diimine and aq. Ni(II) salt under N2 for 3-6h; cooling;; washing with cold methanol and finally with hexane; drying over fused CaCl2 (vac.); elem. anal.;;