8-phenyl-1-naphthalenyl boronic acid

Base Information

• Chemical Name: 8-phenyl-1-naphthalenyl boronic acid
• CAS No.: 181135-36-4
• Molecular Formula: C16H13BO2
• Molecular Weight: 248.08422
• Mol file: 181135-36-4.mol

Synonyms:8-phenyl-1-naphthalenyl boronic acid

Chemical Property of 8-phenyl-1-naphthalenyl boronic acid

Chemical Property:

• Density: 1.23±0.1 g/cm3 (20 ºC 760 Torr)

Purity/Quality:

99.50% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8-phenyl-1-naphthalenyl boronic acid

There total 6 articles about 8-phenyl-1-naphthalenyl boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

Trimethyl borate (121-43-7,63156-11-6) + 1-bromo-8-phenylnaphthalene (1121545-24-1) → (8-phenylnaphthalene-1-yl)boronic acid (181135-36-4)

Guidance literature:

1-bromo-8-phenylnaphthalene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.833333h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 ℃; for 0.833333h; Inert atmosphere;

Reference yield: 71.0%

Trimethyl borate (121-43-7,63156-11-6) + 1-bromo-8-phenylnaphthalene (1121545-24-1) + water (7732-18-5) → (8-phenylnaphthalene-1-yl)boronic acid (181135-36-4)

Guidance literature:

1-bromo-8-phenylnaphthalene; With n-butyllithium; In hexane; at -78 ℃; for 0.833333h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 3.8h;

water; With ammonium chloride; In tetrahydrofuran;

Reference yield:

Triisopropyl borate (5419-55-6) + 1-bromo-8-phenylnaphthalene (1121545-24-1) → (8-phenylnaphthalene-1-yl)boronic acid (181135-36-4)

Guidance literature:

1-bromo-8-phenylnaphthalene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;

Triisopropyl borate; In tetrahydrofuran; at 20 ℃; for 3h;

upstream raw materials:

Trimethyl borate

1-bromo-8-phenylnaphthalene

water

1,8-dibromonaphthalene